Diisoamyl (1R, 4S)-7-oxabicyclo[2.2.1]hept-5-ene-2,3-dicarboxylate

被引：0

作者：

Quillian, Brandon ^{[1
]}

Musso, Kennedy ^{[1
]}

Vinson, Elizabeth M. ^{[1
]}

Bazemore, Joseph G. ^{[1
]}

Marks, Allison R. ^{[1
]}

Padgett, Clifford W. ^{[1
]}

机构：

[1] Georgia Southern Univ, Dept Biochem Chem & Phys, Armstrong Campus, Savannah, GA 31419 USA

来源：

MOLBANK | 2024年 / 2024卷 / 03期

基金：

美国国家科学基金会;

关键词：

Diels-Alder; Fischer Esterification; Grubb's catalysis monomer; isoamyl ester; 7-oxabicyclo[2.2.1]hept-5-ene-2,3-dicarboxylate; 7-oxanorbornene diesters; OPENING METATHESIS POLYMERIZATION; QUANTITATIVE-ANALYSIS; CHEMISTRY; CRYSTAL;

D O I：

10.3390/M1852

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Diisoamyl (1R,4S)-7-oxabicyclo[2.2.1]hept-5-ene-2,3-dicarboxylate (2) was prepared by reacting exo-7-oxabicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride (1) with isoamyl alcohol in the presence of a sulfuric acid catalyst under sonication conditions. Compound 2 was characterized by H-1, C-13 NMR, DEPT-135, infrared, and UV-vis spectroscopy. Gas chromatography-mass spectrometry, elemental analysis, and melting point determination were used to assess purity. The structure of compound 2 was also determined by single-crystal X-ray diffraction. It crystallizes in the monoclinic space group P2(1)/c (14) with cell values of a = 15.5647(3) & Aring;, b = 12.8969(2) & Aring;, c = 9.0873(2) & Aring;; beta= 99.3920(10)degrees.

引用

页数：8

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