Oxide Solid Electrolytes in Solid-State Batteries

被引：3

作者：

Umair, Muhammad ^{[1
,2
]}

Zhou, Shiqiang ^{[1
,2
]}

Li, Wenzheng ^{[1
,2
]}

Rana, Hafiz Talha Hasnain ^{[1
,2
]}

Yang, Jingyi ^{[1
,2
]}

Cheng, Lukuan ^{[1
,2
]}

Li, Mengrui ^{[1
,2
]}

Yu, Suzhu ^{[1
,2
]}

Wei, Jun ^{[1
,2
,3
]}

机构：

[1] Harbin Inst Technol Shenzhen, Sch Mat Sci & Engn, Shenzhen 518055, Peoples R China

[2] Harbin Inst Technol Shenzhen, Shenzhen Key Lab Flexible Printed Elect Technol, Shenzhen 518055, Peoples R China

[3] Harbin Inst Technol Shenzhen, State Key Lab Adv Welding & Joining, Shenzhen 518055, Peoples R China

来源：

BATTERIES & SUPERCAPS | 2025年 / 8卷 / 06期

关键词：

Oxide solid electrolytes; Solid-state batteries; Ionic conductivity; Stability issues; LITHIUM-ION CONDUCTIVITY; TRANSPORT-PROPERTIES; INTERFACIAL RESISTANCE; CHEMICAL-STABILITY; ELECTROCHEMICAL PERFORMANCE; SINTERING TEMPERATURE; SUPERIONIC CONDUCTOR; LI+ CONDUCTIVITY; GLASS-CERAMICS; THIN-FILMS;

D O I：

10.1002/batt.202400667

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Solid-state electrolytes (SSEs) have re-emerged as high-priority materials for enhancing the safety and power density of electrochemical energy storage devices. However, several challenges, including low ionic conductivity, narrow redox windows, and interface issues, hinder the practical deployment of solid-state batteries (SSBs). In this review, we evaluate recent advances in the design, synthesis, and analysis of oxide SSEs and identify relevant structural and stability factors, as well as dimensional design concepts, for creating oxide SSEs to meet practical application requirements. We provide an overview of the development and characteristics of oxide SSEs, then analyze bulk and ion transport based on different structures. We summarize the progress made in various synthetic approaches to oxide SSEs and discuss issues related to their stability and factors influencing ionic conductivity. Furthermore, we present the main challenges and future development directions of oxide SSBs to pave the way for the practical applications of oxide SSEs.

引用

页数：28

共 213 条

[1] Dual-Doped Cubic Garnet Solid Electrolytes with Superior Air Stability [J].

Abrha, Ljalem Hadush ;

Hagos, Tesfaye Teka ;

Nikodimos, Yosef ;

Bezabh, Hailemariam Kassa ;

Berhe, Gebregziabher Brhane ;

Hagos, Teklay Mezgebe ;

Huang, Chen-Jui ;

Tegegne, Wodaje Addis ;

Jiang, Shi-Kai ;

Weldeyohannes, Haile Hisho ;

Wu, She-Huang ;

Su, Wei-Nien ;

Hwang, Bing Joe .

ACS APPLIED MATERIALS & INTERFACES, 2020, 12 (23) :25709-25717

[2] Electrochemical performance of a garnet solid electrolyte based lithium metal battery with interface modification [J].

Alexander, George V. ;

Rosero-Navarro, Nataly Carolina ;

Miura, Akira ;

Tadanaga, Kiyoharu ;

Murugan, Ramaswamy .

JOURNAL OF MATERIALS CHEMISTRY A, 2018, 6 (42) :21018-21028

[3] Fast microwave-assisted synthesis of Li-stuffed garnets and insights into Li diffusion from muon spin spectroscopy [J].

Amores, Marco ;

Ashton, Thomas E. ;

Baker, Peter J. ;

Cussen, Edmund J. ;

Corr, Serena A. .

JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (05) :1729-1736

[4] IONIC-CONDUCTIVITY OF SOLID ELECTROLYTES BASED ON LITHIUM TITANIUM PHOSPHATE [J].

AONO, H ;

SUGIMOTO, E ;

SADAOKA, Y ;

IMANAKA, N ;

ADACHI, G .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1990, 137 (04) :1023-1027

[5] Inorganic Solid-State Electrolytes for Lithium Batteries: Mechanisms and Properties Governing Ion Conduction [J].

Bachman, John Christopher ;

Muy, Sokseiha ;

Grimaud, Alexis ;

Chang, Hao-Hsun ;

Pour, Nir ;

Lux, Simon F. ;

Paschos, Odysseas ;

Maglia, Filippo ;

Lupart, Saskia ;

Lamp, Peter ;

Giordano, Livia ;

Shao-Horn, Yang .

CHEMICAL REVIEWS, 2016, 116 (01) :140-162

[6] Interfaces and Interphases in All-Solid-State Batteries with Inorganic Solid Electrolytes [J].

Banerjee, Abhik ;

Wang, Xuefeng ;

Fang, Chengcheng ;

Wu, Erik A. ;

Meng, Ying Shirley .

CHEMICAL REVIEWS, 2020, 120 (14) :6878-6933

[7] Nanoscale Synthesis of Li1.3Al0.3Ti1.7(PO4)3 Solid-State Lithium Ion Battery Electrolyte: A Structural and Ionic Conductivity Study [J].

Bharathi, Pandiyan ;

Wang, Sea-Fue .

ACS APPLIED NANO MATERIALS, 2024, 7 (02) :1615-1624

[8] Comparison of computational methods for the electrochemical stability window of solid-state electrolyte materials [J].

Binninger, Tobias ;

Marcolongo, Aris ;

Mottet, Matthieu ;

Weber, Valery ;

Laino, Teodoro .

JOURNAL OF MATERIALS CHEMISTRY A, 2020, 8 (03) :1347-1359

[9] Lithium solid-state batteries: State-of-the-art and challenges for materials, interfaces and processing [J].

Boaretto, Nicola ;

Garbayo, Inigo ;

Valiyaveettil-SobhanRaj, Sona ;

Quintela, Amaia ;

Li, Chunmei ;

Casas-Cabanas, Montse ;

Aguesse, Frederic .

JOURNAL OF POWER SOURCES, 2021, 502

[10] PHASE-TRANSFORMATION IN NA1+XSIXZR2P3-XO12 COMPOUNDS [J].

BOILOT, JP ;

SALANIE, JP ;

DESPLANCHES, G ;

LEPOTIER, D .

MATERIALS RESEARCH BULLETIN, 1979, 14 (11) :1469-1477

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