Crystal structure of bis(β-alaninium) tetrabromidoplumbate

被引:0
|
作者
Tonoyan, Gayane S. [1 ]
Giester, Gerald [2 ]
Ghazaryan, Vahram V. [1 ]
Chilingaryan, Ruben Yu. [1 ]
Margaryan, Arthur A. [1 ]
Mkrtchyan, Artak H. [1 ]
Petrosyan, Aram M. [1 ]
机构
[1] NAS Armenia, Inst Appl Problems Phys, 25 Nersessyan Str, Yerevan 0014, Armenia
[2] Univ Vienna, Inst Mineral & Crystallog, Josef Holaubek Pl 2, A-1090 Vienna, Austria
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2024年 / 80卷
关键词
organic-inorganic crystal; hybrid crystal; bromoplumbate; crystal structure; HYBRID PEROVSKITE;
D O I
10.1107/S2056989024007722
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, poly[bis(beta-alaninium) [[dibromidoplumbate]-di-mu-dibromido]] {(C2H8NO2)(2)[PbBr4]}(n) or (beta-AlaH)(2)PbBr4, crystallizes in the monoclinic space group P2(1)/n. The (PbBr4)(2-) anion is located on a general position and has a two-dimensional polymeric structure. The Pb center is holodirected. The supramolecular network is mainly based on O-H center dot center dot center dot Br, N-H center dot center dot center dot Br and N-H center dot center dot center dot O hydrogen bonds.
引用
收藏
页码:931 / +
页数:10
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