Transition-Metal-Free Thioboration of Terminal Alkynes

被引：0
作者：
Matsuyama, Taro [1 ]
Ishida, Hiroshi [1 ]
Wang, Chao [2 ]
Miyamoto, Kazunori [1 ,3 ]
Nakajima, Masaya [1 ]
Toriumi, Naoyuki [1 ]
Nagashima, Yuki [1 ]
Uchiyama, Masanobu [1 ,4 ]
机构：
[1] Univ Tokyo, Grad Sch Pharmaceut Sci, Tokyo 1130033, Japan
[2] Kanazawa Univ, Fac Pharmaceut Sci, Inst Med Pharmaceut & Hlth Sci, Kanazawa, Ishikawa 9201192, Japan
[3] Keio Univ, Fac Pharm, Tokyo 1058512, Japan
[4] Shinshu Univ, Res Initiat Supramat RISM, Ueda, Nagano 3868567, Japan
来源：
JACS AU | 2024年
关键词：
thioboration; elementoboration; vinyl sulfide; vinyl boron; dual functionalization; alkyne; UNSATURATED-COMPOUNDS; ALLIED REACTIONS; VINYL SULFIDES; PALLADIUM; HYDROBORATION; HALOBORATION; SILABORATION; DIBORATION; CATALYSIS; OLEFINS;
D O I：
10.1021/jacsau.4c00907
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We present a new type of elementoboration reaction, the thioboration of terminal alkynes. This method enables highly controllable regio-/stereo-/chemoselective cis- and trans-thioboration on demand, affording synthetically versatile and densely functionalized vinyl boron/vinyl sulfide derivatives in a straightforward manner without the need for a transition-metal catalyst.
引用
收藏
页码：4927 / 4933
页数：7
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