Visible light-driven CoMoO4/g-C3N4 photocatalyst for removal of antibiotic contaminant from wastewater

被引:3
作者
Jitae, Kim [1 ,2 ]
Nguyen, Minh Viet [3 ]
Huong, Pham Thi [4 ]
机构
[1] Duy Tan Univ, Inst Res & Dev, Da Nang, Vietnam
[2] Duy Tan Univ, Sch Engn & Technol, Da Nang, Vietnam
[3] VNU Univ Sci, Fac Chem, VNU Key Lab Adv Mat Green Growth, 334 Nguyen Trai St, Thanh Xuan, Hanoi, Vietnam
[4] Gachon Univ, Dept Mat Sci & Engn, 1342 Seongnam daero, Seongnam 13120, South Korea
关键词
Antibiotic pollutants; Heterojunction photocatalyst; Wastewater; CoMoO4;
D O I
10.1016/j.matchemphys.2025.130433
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this work, CoMoO4/g-C3N4 heterojunction photocatalyst was synthesized and utilized to enhance the photo- degradation efficiency of the tetracycline antibiotic pollutant (A-TC) in wastewater. The results from UV-Vis and photoluminescence analysis indicate that the optical properties and the separation rate of photogenerated electrons/holes in the CoMoO4/g-C3N4 heterojunction photocatalyst are significantly improved. Under the same conditions, CoMoO4/g-C3N4 heterojunction photocatalyst effectively removed 91.3 % of A-TC from the solution, which is significantly higher than the removal efficiencies of g-C3N4 (68.7 %) and CoMoO4 (57.9 %). Moreover, the photodegradation efficiency of A-TC in wastewater using CoMoO4/g-C3N4 was 80.2 %, suggesting the potential of the synthesized heterojunction photocatalyst for practical water treatment. In addition, the proposed degradation mechanism of A-TC using the CoMoO4/g-C3N4 heterojunction photocatalyst is founded on the Zscheme and the role of free radicals.
引用
收藏
页数:9
相关论文
共 50 条
[31]   Photocatalytic degradation of phenol wastewater over Z-scheme g-C3N4/CNT/BiVO4 heterostructure photocatalyst under solar light irradiation [J].
Samsudin, Mohamad Fakhrul Ridhwan ;
Bacho, Nurfatien ;
Sufian, Suriati ;
Ng, Yun Hau .
JOURNAL OF MOLECULAR LIQUIDS, 2019, 277 :977-988
[32]   Enhanced LED-light-driven photocatalytic antibacterial by g-C3N4/BiOI composites [J].
Li, Yeping ;
Wang, Qian ;
Huang, Liying ;
Xu, Xiuquan ;
Xie, Meng ;
Wang, Hao ;
Huang, Shuquan ;
Zhang, Fei ;
Zhao, Zhengyun ;
Yang, Juan .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2019, 30 (03) :2783-2794
[33]   Synthesis of new photocatalyst based on g-C3N4/N,P CQD/ZIF-67 nanocomposite for ciprofloxacin degradation under visible light irradiation [J].
Teymourinia, Hakimeh ;
Alshamsi, Hassan Abbas ;
Al-nayili, Abbas ;
Sohouli, Esmail ;
Gholami, Mitra .
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2023, 125 :259-268
[34]   Construction of g-C3N4/Bi4Ti3O12 hollow nanofibers with highly efficient visible-light-driven photocatalytic performance [J].
Shi, Hongfei ;
Fu, Jinchang ;
Jiang, Wei ;
Wang, Yueting ;
Liu, Baolei ;
Liu, Junxi ;
Ji, Haifeng ;
Wang, Weidong ;
Chen, Zhe .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2021, 615
[35]   Boosting visible light photocatalytic performance of g-C3N4 nanosheets by combining with LaFeO3 nanoparticles [J].
Jin, Luo ;
Zhou, Xiaosong ;
Ning, Xiaomei ;
Zhan, Liang ;
Kong, Minjian ;
Tan, Kangfeng ;
Li, Jinxian ;
Lin, Zhuojia .
MATERIALS RESEARCH BULLETIN, 2018, 102 :353-361
[36]   Hydrothermal Construction and Visible-Light Driven Photodegradation Performance of CuIn11S17/g-C3N4 Heterojunction [J].
Feng, Xiao-Qiang ;
Zhou, Min ;
Du, Yan ;
Cai, Jia-Yi ;
Bi, Jin-Yan ;
Wang, Jing-Yi ;
Wang, Yan-Dong ;
Li, Xiao-Fang .
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2025, 70 (02) :306-318
[37]   Construction of Ag/g-C3N4 photocatalysts with visible-light photocatalytic activity for sulfamethoxazole degradation [J].
Song, Yali ;
Qi, Jingyao ;
Tian, Jiayu ;
Gao, Shanshan ;
Cui, Fuyi .
CHEMICAL ENGINEERING JOURNAL, 2018, 341 :547-555
[38]   g-C3N4/TiO2 Nanocomposites for Degradation of Ciprofloxacin under Visible Light Irradiation [J].
Yang, Zhen ;
Yan, Jia ;
Lian, Jiabiao ;
Xu, Hui ;
She, Xiaojie ;
Li, Huaming .
CHEMISTRYSELECT, 2016, 1 (18) :5679-5685
[39]   Enhanced photocatalytic degradation of rhodamine B and malachite green employing BiFeO3/g-C3N4 nanocomposites: An efficient visible-light photocatalyst [J].
Mohanty, Lopamudra ;
Singhal, Rahul ;
Pradhan, Debapriya ;
Pattanayak, Dhruti Sundar ;
Dash, Suresh Kumar .
INORGANIC CHEMISTRY COMMUNICATIONS, 2022, 138
[40]   Visible-light-driven photocatalytic removal of antibiotics by newly designed C3N4@MnFe2O4-graphene nanocomposites [J].
Wang, Xiangyu ;
Wang, Anqi ;
Ma, Jun .
JOURNAL OF HAZARDOUS MATERIALS, 2017, 336 :81-92