Green synthesis of reduced graphene oxide nanosheets: An efficient material for electrochemical sensor and photocatalytic agent

被引:7
作者
Liang, Yujie [1 ]
Liao, Haiyan [2 ]
Gong, Sheng [1 ]
Lan, Licai [1 ]
Hasan, Murtaza [1 ]
Zhou, Xinhua [1 ,3 ]
Gunasekaran, Sundaram [4 ]
机构
[1] Zhongkai Univ Agr & Engn, Coll Chem & Chem Engn, Guangzhou 510225, Guangdong, Peoples R China
[2] Zhongkai Univ Agr & Engn, Dev Planning Dept, Guangzhou 510225, Guangdong, Peoples R China
[3] Zhongkai Univ Agr & Engn, Guangzhou Key Lab Efficient Utilizat Agrochem, Guangzhou 510225, Peoples R China
[4] Univ Wisconsin Madison, Dept Biol Syst Engn, Madison, WI 53706 USA
关键词
Reduced graphene oxide; Green synthesis; Electrochemical sensor; Cd(II) detection; Photocatalytic agent; Plumeria alba flower extracts; METHYLENE-BLUE; REDUCTION; NANOPARTICLES; DEGRADATION; DYE; NANOCOMPOSITE;
D O I
10.1016/j.microc.2025.112799
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Here in this report, Plumeria alba flower extracts (PAFE) were used as a green reducing agent for the synthesis of reduced graphene oxide (rGO), and the metamorphosis of rGO was characterized via Ultraviolet-Visible (UV-Vis), Fourier Transform Infrared Spectroscopy (FT-IR), and X-ray photoelectron spectroscopic (XPS). The results show that the 7.5rGO has the highest efficiency in electronic transmission for smaller Delta Ep facilitating a faster rate of electron transfer. As the differential pulse stripping voltammetry (DPSV) responses of 7.5rGO-modified glassy carbon electrode (GCE) to Cd(II) concentrations ranging from 0.0084 to 1.12 mg/L, demonstrating a linear correlation between the peak current and Cd(II) concentration. Meanwhile, under UV irradiation, 7.5rGO achieved a degradation rate of 65.62 % for the Methylene blue (MB) dye, with a degradation rate constant of 0.00827 min-1. This study establishes an environmentally friendly reduction method for the synthesis of rGO using plant extracts as reducing agents. The resulting rGO emerges as a powerful platform, poised to revolutionize the electrochemical determination of heavy metal ions and the degradation of organic dyes.
引用
收藏
页数:11
相关论文
共 77 条
[1]   Development of green photocatalyst using empty fruit bunches from Elaeis guineensis for methylene blue degradation [J].
Abd Rani, Umairah ;
Ng, Law Yong ;
Ng, Ching Yin ;
Chiew, Chia Min ;
Mahmoudi, Ebrahim ;
Ong, Chin Boon ;
Hairom, Nur Hanis Hayati .
JOURNAL OF MOLECULAR STRUCTURE, 2023, 1282
[2]   A Potentiometric Sensor for Cd2+ Based on Carbon Nanotube Paste Electrode Constructed from Room Temperature Ionic Liquid, Ionophore and Silica Nanoparticles [J].
Afkhami, Abbas ;
Bagheri, Hasan ;
Shirzadmehr, Ali ;
Khoshsafar, Hosein ;
Hashemi, Pegah .
ELECTROANALYSIS, 2012, 24 (11) :2176-2185
[3]   Chemically modified alumina nanoparticles for selective solid phase extraction and preconcentration of trace amounts of Cd(II) [J].
Afkhami, Abbas ;
Madrakian, Tayyebeh ;
Ahmadi, Reza ;
Bagheri, Hasan ;
Tabatabaee, Masoumeh .
MICROCHIMICA ACTA, 2011, 175 (1-2) :69-77
[4]   Reduction of graphene oxide using Salvia Officinalis plant extract and its utilization for Li-O2 batteries [J].
Al-Ogaili, Ahmed Waleed Majeed ;
Pakseresht, Sara ;
Cetinkaya, Tugrul ;
Akbulut, Hatem .
DIAMOND AND RELATED MATERIALS, 2022, 126
[5]   Lithium Aluminum Hydride as Reducing Agent for Chemically Reduced Graphene Oxides [J].
Ambrosi, Adriano ;
Chua, Chun Kiang ;
Bonanni, Alessandra ;
Pumera, Martin .
CHEMISTRY OF MATERIALS, 2012, 24 (12) :2292-2298
[6]   The green reduction of graphene oxide [J].
Aunkor, M. T. H. ;
Mahbubul, I. M. ;
Saidur, R. ;
Metselaar, H. S. C. .
RSC ADVANCES, 2016, 6 (33) :27807-27828
[7]   Deoxygenation of graphene oxide using household baking soda as a reducing agent: a green approach [J].
Aunkor, M. T. H. ;
Mahbubul, I. M. ;
Saidur, R. ;
Metselaar, H. S. C. .
RSC ADVANCES, 2015, 5 (86) :70461-70472
[8]   Tuning the surface functionalities, textural properties and capacitance properties of reduced graphene oxide by utilizing environmentally threatening invasive weed as a reducing agent [J].
Bharathidasan, P. ;
Subramaniam, Thiruvenkatam ;
Sunju, N. M. ;
Sivakkumar, S. R. ;
Devaraj, S. .
JOURNAL OF ENERGY STORAGE, 2021, 42
[9]   The capacitance properties of nitrogen doped reduced graphene oxide obtained by using commercial protein powder as a nitrogen dopant [J].
Bharathidasan, P. ;
Devaraj, S. ;
Sivakkumar, S. R. .
JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2020, 24 (05) :1095-1103
[10]   Enhanced capacitance properties of nitrogen doped reduced graphene oxide obtained by simultaneous reduction and nitrogen doping [J].
Bharathidasan, P. ;
Idris, Mustapha Balarabe ;
Kim, Dong-Won ;
Sivakkumar, S. R. ;
Devaraj, S. .
FLATCHEM, 2018, 11 :24-31