Synthesis of 1,1-diethoxyethane from ethanol using electrogenerated acid

被引：0

作者：

Kasahara, Taichi ^{[1
]}

Kawaguchi, Daisuke ^{[1
]}

Kurokawa, Hideki ^{[1
]}

Ogihara, Hitoshi ^{[1
]}

机构：

[1] Saitama Univ, Grad Sch Sci & Engn, 255 Shimo Okubo,Sakura Ku, Saitama 3388570, Japan

来源：

CHEMISTRY LETTERS | 2024年 / 53卷 / 11期

基金：

日本学术振兴会;

关键词：

electrogenerated acid; ethanol; oxidation; COMPOUND; CATALYST;

D O I：

10.1093/chemle/upae194

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We introduce a novel reaction where electrogenerated acid enhances ethanol upgrading. Electrochemical oxidation of ethanol produces acetaldehyde and protons; the protons act as electrogenerated acid, catalyzing acetalization to form 1,1-diethoxyethane. Stirring the solution shifts the reaction toward acetaldehyde production because electrogenerated acid is neutralized by an electrogenerated base at the cathode.

引用

页数：5

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