Flower-like WO3 Nanorod Structures Modified with MoS2 Quantum Dots for Low-Temperature Acetone Detection

被引:1
作者
Shang, Jichao [1 ,2 ,3 ]
Zhou, Mingyue [1 ,2 ]
Xie, Fuwei [3 ]
Li, Shuqi [3 ]
Tu, Shiyu [3 ]
Liu, Xiangrui [3 ]
Zhang, Lu [1 ,2 ]
机构
[1] Xinjiang Univ, Sch Pharmaceut Sci, Urumqi 830017, Peoples R China
[2] Xinjiang Univ, Inst Mat Med, Urumqi 830017, Peoples R China
[3] Xinjiang Univ, Coll Life Sci & Technol, Xinjiang Key Lab Biol Resources & Genet Engn, Urumqi 830046, Peoples R China
关键词
acetone; WO3; MoS2; gas sensors; quantum dots; n-n junction; SENSOR; SENSITIVITY; NANOSHEETS; ETHANOL; BREATH;
D O I
10.1021/acsanm.4c06344
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
As a prevalent volatile organic compound (VOC), acetone plays a significant role in diverse domains, such as environmental protection, industrial production, and medical diagnosis. However, if acetone is not adequately monitored and disposed of, it can result in immeasurable adverse effects on human health and the natural environment. Therefore, it is essential to realize the highly sensitive, convenient, and efficient real-time detection of acetone. In this study, MoS2 quantum dots (QDs) were modified on flower-like WO3 nanorod structure through the hydrothermal approach to fabricate a WO3/MoS2 sensor. The sensing performance of the sensor for acetone was investigated. The results showed that the sensor had a response value of 14.96 for 30 ppm of acetone gas at optimum operating temperature (132 degrees C), which was 3.2 times the performance of a pure WO3 gas sensor. The response of the WO3/MoS2 sensor was reduced by only 20% under a relative humidity of 85%. Besides, the sensor still maintained a high response (11.25 for 30 ppm) under high curvature conditions (120 degrees). Finally, the sensitization effects of MoS2 QDs, including the formation of n-n heterojunction with WO3 and the catalytic overflow of oxygen species, were discussed in detail. This study provides a valuable reference for the construction of low-temperature and high-performance gas sensors based on QD-sensitized metal oxide nanomaterials.
引用
收藏
页码:28818 / 28828
页数:11
相关论文
共 56 条
  • [51] Selectivity and sensitivity of Pd-loaded and Fe-doped SnO2 sensor for CO detection
    Yin, Xi-Tao
    Guo, Xing-Min
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 2014, 200 : 213 - 218
  • [52] Fe2O3 Nanorod/Bacterial Cellulose Carbon Nanofiber Composites for Enhanced Acetone Sensing
    Zhai, Xinwang
    Wu, Zhaofeng
    Sun, Qihua
    Sun, Jun
    Tursun, Rabigul
    Zhang, Min
    Duan, Haiming
    Zhang, Dongzhi
    [J]. ACS APPLIED NANO MATERIALS, 2023, 6 (13) : 12168 - 12176
  • [53] Metal-organic frameworks-derived zinc oxide nanopolyhedra/S, N: graphene quantum dots/polyaniline ternary nanohybrid for high-performance acetone sensing
    Zhang, Dongzhi
    Wu, Zhenling
    Zong, Xiaoqi
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 2019, 288 : 232 - 242
  • [54] Fabrication of conductive graphene oxide-WO3 composite nanofibers by electrospinning and their enhanced acetone gas sensing properties
    Zhang, Jinniu
    Lu, Hongbing
    Yan, Chao
    Yang, Zhibo
    Zhu, Gangqiang
    Gao, Jianzhi
    Yin, Feng
    Wang, Chunlan
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 2018, 264 : 128 - 138
  • [55] One-Dimensional MoS2-Decorated TiO2 nanotube gas sensors for efficient alcohol sensing
    Zhao, P. X.
    Tang, Y.
    Mao, J.
    Chen, Y. X.
    Song, H.
    Wang, J. W.
    Song, Y.
    Liang, Y. Q.
    Zhang, X. M.
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2016, 674 : 252 - 258
  • [56] Bi-functional Mo-doped WO3 nanowire array electrochromism-plus electrochemical energy storage
    Zhou, D.
    Shi, F.
    Xie, D.
    Wang, D. H.
    Xia, X. H.
    Wang, X. L.
    Gu, C. D.
    Tu, J. P.
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2016, 465 : 112 - 120