Synthesis of chromophores with efficient near-infrared (NIR) light absorption, combined with high stability and photoactivity, remains a significant challenge in materials science. This study explores the enhancement of Azadipyrromethenes (ADPMs) through the incorporation of ferrocene, zinc, and boron. We provide synthesis and characterization data demonstrating that these modifications markedly improve the photophysical and electrochemical properties of ADPMs. The addition of metal centers increases molar absorptivity and alters redox behavior, while ferrocene substitution refines the electronic and steric properties. Structural analysis, including X-ray crystallography, reveals significant changes in bond angles and molecular conformation. The modified ADPMs exhibit enhanced absorption and stability, showcasing their potential for use in imaging, sensing, and phototherapy. This research underscores the transformative impact of integrating metal centers and ferrocene groups into chromophore technology, paving the way for future advances in scientific and technological applications.
