Study on the synthesis of bisphenol S by reactive dehydration in rotating packed bed

被引：0

作者：

He, Ming-Tao ^{[1
,2
]}

Li, Peng ^{[1
,2
]}

Wang, Yin-Hao ^{[1
,2
]}

Du, Lei ^{[1
,2
]}

Huang, Song ^{[3
]}

Zou, Hai-Kui ^{[1
,2
]}

Chu, Guang-Wen ^{[1
,2
]}

Sun, Bao-Chang ^{[1
,2
]}

机构：

[1] Beijing Univ Chem Technol, Res Ctr, Minist Educ High Grav Engn & Technol, Beijing 100029, Peoples R China

[2] Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China

[3] Quzhou Innovat Inst Chem Engn & Mat, Quzhou 324000, Peoples R China

来源：

CHEMICAL ENGINEERING SCIENCE | 2025年 / 305卷

基金：

中国国家自然科学基金; 国家重点研发计划;

关键词：

Bisphenol S; Reactive dehydration; High gravity technology; Rotating packed bed; PROCESS INTENSIFICATION; MASS-TRANSFER; TECHNOLOGY; NANOPARTICLES; PERFORMANCE;

D O I：

10.1016/j.ces.2025.121182

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

In this work, the synthesis of bisphenol S (4,4 '-BPS) using reactive dehydration in a rotating packed bed (RPB) was studied. Firstly, orthogonal experiments were adopted to investigate the effects of different operating conditions on the yield and content of 4,4 '-BPS in a stirred tank reactor (STR), including the mesitylene/phenol molar ratio (mu), reflux dehydration time (t), and stirring speed (n), in order to optimize the operating conditions in STR. Based on the study in STR, the effects of operating conditions, including rotation speed (N), feeding rate (q), and cycle number (tau), on the yield and content of 4,4 '-BPS in RPB combined with STR (RPB-STR) were further investigated to optimize the operating conditions. The results indicated that compared to STR, the yield and content of 4,4 '-BPS increased by 22.1% and 7.52% under the optimal operating conditions in RPB-STR, respectively. This work provides a novel route for efficient synthesizing 4,4 '-BPS.

引用

页数：8

共 40 条

[1] Bisphenol A and replacements in thermal paper: A review [J].

Bjornsdotter, Maria K. ;

de Boer, Jacob ;

Ballesteros-Gomez, Ana .

CHEMOSPHERE, 2017, 182 :691-706

[2] Process intensification: Visual study of liquid maldistribution in rotating packed beds [J].

Burns, JR ;

Ramshaw, C .

CHEMICAL ENGINEERING SCIENCE, 1996, 51 (08) :1347-1352

[3] Flow and Surface Renewal of the Viscous Filaments in a High-Speed Disperser [J].

Cai, Lile ;

Ouyang, Yi ;

Liang, Wenjun ;

Gao, Zhengming ;

Cai, Ziqi .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2019, 58 (49) :22427-22439

[4] Synthesis of nanoparticles with novel technology: High-gravity reactive precipitation [J].

Chen, JF ;

Wang, YH ;

Guo, F ;

Wang, XM ;

Zheng, C .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2000, 39 (04) :948-954

[5] Recent advances in nanoparticles production by high gravity technology - from fundamentals to commercialization [J].

Chen, Jian-Feng ;

Shao, Lei .

JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 2007, 40 (11) :896-904

[6] Optimization of Preparation of Foamed Concrete Based on Orthogonal Experiment and Range Analysis [J].

Cong, Menglong ;

Zhang, Shanshan ;

Sun, Dandan ;

Zhou, Kunpeng .

FRONTIERS IN MATERIALS, 2021, 8 (08)

[7]

Dang Wei-min, 2008, Zhonghua Lao Dong Wei Sheng Zhi Ye Bing Za Zhi, V26, P457

[8]

Eiji-Wakagawacho O., 1994, EP Pat, Patent No. 0443046

[9] Synchronous visual and RTD study on liquid flow in rotating packed-bed contactor [J].

Guo, K ;

Guo, F ;

Feng, YD ;

Chen, JF ;

Zheng, C ;

Gardner, NC .

CHEMICAL ENGINEERING SCIENCE, 2000, 55 (09) :1699-1706

[10] Computational Fluid Dynamics Analysis of the Micromixing Efficiency in a Rotating-Packed-Bed Reactor [J].

Guo, Tian-Yu ;

Shi, Xin ;

Chu, Guang-Wen ;

Xiang, Yang ;

Wen, Li-Xiong ;

Chen, Jian-Feng .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2016, 55 (17) :4856-4866

← 1 2 3 4 →