AFM and DFT study of diverse self-organization pattern of aminothiacalix[4]arene

被引：1

作者：

Karalash, Sergey A. ^{[1
]}

Botnar, Anna A. ^{[1
]}

Aglikov, Aleksandr S. ^{[1
]}

Muraveva, Ekaterina A. ^{[1
]}

Kozodaev, Dmitry A. ^{[2
]}

Novikov, Alexander S. ^{[1
]}

Skorb, Ekaterina V. ^{[1
]}

Muravev, Anton A. ^{[1
]}

机构：

[1] ITMO Univ, Infochem Sci Ctr, 9 Lomonosov Str, St Petersburg 191002, Russia

[2] NT MDT BV, NL-7327 Apeldoorn, Netherlands

来源：

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY | 2025年

关键词：

Aminothiacalix[4]arene; Atomic force microscopy; Density functional theory; Energy-dispersive X-ray spectroscopy; RECEPTOR; BINDING;

D O I：

10.1007/s10847-025-01285-1

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Here we report on the diverse self-assembly behavior of aminothiacalix[4]arene (ATCA) drop-casted or spin-coated onto a silicon substrate. The nanofilms of ATCA feature the picket-fence domains composed of rod-shaped crystals with the mean size of ca. 700 nm, as well as the ornate patterns composed of interdigitating 3.5-mu m grooves and periodically alternating ridge-like framework, with the ridge diameter 90 +/- 20 nm and ridge spacing of ca. 3.5 mu m. DFT calculation of possible ATCA dimers revealed a favorable arrangement of ATCA monomers either in a face parallel fashion expanding into the 1D channel structure or in a face antiparallel fashion affording the 1D zigzag chain structure. UV/Vis spectroscopy and powder X-ray diffraction data provided further evidence to the existence of thermodynamically favorable pi-stacked and hydrogen-bonded ATCA associates in solution and solid state.

引用

页码：133 / 140

页数：8