Structural and magnetic properties of Fe2TeO6-α-Fe2O3 nanocomposite

被引:0
作者
Saini, Aarti [1 ]
Bhedi, Dharmveer [1 ]
Verma, Mukesh [2 ]
Meena, Sher Singh [3 ]
Bitla, Yugandhar [2 ]
Thirumoorthi, Ramalingam [1 ]
机构
[1] Cent Univ Rajasthan, Sch Chem Sci & Pharm, Dept Chem, Ajmer 305817, India
[2] Cent Univ Rajasthan, Dept Phys, Sch Phys Sci, Ajmer 305817, India
[3] Bhabha Atom Res Ctr, Solid State Phys Div, Mumbai 400085, India
关键词
Iron tellurate; hematite; powder X-ray diffraction; magnetic materials; thermal decomposition; OPTICAL-PROPERTIES; TELLURIUM DIOXIDE; CRYSTAL-STRUCTURE; MOSSBAUER; FERROMAGNETISM; SEMICONDUCTORS; NANOPARTICLES; LATTICE; PARATELLURITE; DYNAMICS;
D O I
10.1007/s12034-024-03396-w
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Iron tellurate-hematite nanocomposite was obtained by the thermal decomposition of organotellurium ferrocenecarboxylate. XRD study revealed that the composite has 68% tetragonal Fe2TeO6 phase and 32% trigonal alpha-Fe2O3 phase. Energy-dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy confirm the chemical homogeneity of the nanocomposite. During the thermal decomposition of the precursor, tellurium segregates out in amorphous form resulting in a proportionate amount of alpha-Fe2O3 phase. Room temperature M & ouml;ssbauer spectrum reveals that Fe is in +3 state in the nanocomposite. The bulk magnetization study reveals room temperature ferromagnetic order in the nanocomposite.
引用
收藏
页数:9
相关论文
共 64 条
[41]   Surface chemical bonding states and ferroelectricity of Ce-doped BiFeO3 thin films prepared by sol-gel process [J].
Quan, Zuci ;
Hu, Hao ;
Xu, Sheng ;
Liu, Wei ;
Fang, Guojia ;
Li, Meiya ;
Zhao, Xingzhong .
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2008, 48 (03) :261-266
[42]   Assessing magnetic and inductive thermal properties of various surfactants functionalised Fe3O4 nanoparticles for hyperthermia [J].
Rajan, Arunima ;
Sharma, Madhulika ;
Sahu, Niroj Kumar .
SCIENTIFIC REPORTS, 2020, 10 (01)
[43]  
Saini A, 2024, MATER ADV, V5, P5543, DOI [10.1039/d4ma00077c, 10.1039/D4MA00077C]
[44]   Growing of fixed orientation plane of single crystal using the flux growth technique and ferrimagnetic ordering in Ni3TeO6 of stacked 2D honeycomb rings [J].
Sankar, R. ;
Shu, G. J. ;
Moorthy, B. Karunakara ;
Jayavel, R. ;
Chou, F. C. .
DALTON TRANSACTIONS, 2013, 42 (29) :10439-10443
[45]   Li4NiTeO6 as a positive electrode for Li-ion batteries [J].
Sathiya, M. ;
Ramesha, K. ;
Rousse, G. ;
Foix, D. ;
Gonbeau, D. ;
Guruprakash, K. ;
Prakash, A. S. ;
Doublet, M. L. ;
Tarascon, J. -M. .
CHEMICAL COMMUNICATIONS, 2013, 49 (97) :11376-11378
[46]   Zinc oxide-based diluted magnetic semiconductors [J].
Seshadri, Ram .
CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 2005, 9 (1-2) :1-7
[47]   Facile Growth and Characterization of α-Fe2O3 Nanoparticles for Photocatalytic Degradation of Methyl Orange [J].
Sharma, P. ;
Kumar, R. ;
Chauhan, S. ;
Singh, Dilbag ;
Chauhan, M. S. .
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2014, 14 (08) :6153-6157
[48]   X-RAY AND FAR-UV PHOTOEMISSION FROM AMORPHOUS AND CRYSTALLINE FILMS OF SE AND TE [J].
SHEVCHIK, NJ ;
CARDONA, M ;
TEJEDA, J .
PHYSICAL REVIEW B, 1973, 8 (06) :2833-2841
[49]   Ferromagnetism as a universal feature of inorganic nanoparticles [J].
Sundaresan, A. ;
Rao, C. N. R. .
NANO TODAY, 2009, 4 (01) :96-106
[50]   THE CRYSTAL-STRUCTURE AND ABSOLUTE OPTICAL CHIRALITY OF PARATELLURITE, ALPHA-TEO2 [J].
THOMAS, PA .
JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1988, 21 (25) :4611-4627