Structural and magnetic properties of Fe2TeO6-α-Fe2O3 nanocomposite

被引:0
作者
Saini, Aarti [1 ]
Bhedi, Dharmveer [1 ]
Verma, Mukesh [2 ]
Meena, Sher Singh [3 ]
Bitla, Yugandhar [2 ]
Thirumoorthi, Ramalingam [1 ]
机构
[1] Cent Univ Rajasthan, Sch Chem Sci & Pharm, Dept Chem, Ajmer 305817, India
[2] Cent Univ Rajasthan, Dept Phys, Sch Phys Sci, Ajmer 305817, India
[3] Bhabha Atom Res Ctr, Solid State Phys Div, Mumbai 400085, India
关键词
Iron tellurate; hematite; powder X-ray diffraction; magnetic materials; thermal decomposition; OPTICAL-PROPERTIES; TELLURIUM DIOXIDE; CRYSTAL-STRUCTURE; MOSSBAUER; FERROMAGNETISM; SEMICONDUCTORS; NANOPARTICLES; LATTICE; PARATELLURITE; DYNAMICS;
D O I
10.1007/s12034-024-03396-w
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Iron tellurate-hematite nanocomposite was obtained by the thermal decomposition of organotellurium ferrocenecarboxylate. XRD study revealed that the composite has 68% tetragonal Fe2TeO6 phase and 32% trigonal alpha-Fe2O3 phase. Energy-dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy confirm the chemical homogeneity of the nanocomposite. During the thermal decomposition of the precursor, tellurium segregates out in amorphous form resulting in a proportionate amount of alpha-Fe2O3 phase. Room temperature M & ouml;ssbauer spectrum reveals that Fe is in +3 state in the nanocomposite. The bulk magnetization study reveals room temperature ferromagnetic order in the nanocomposite.
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页数:9
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