A novel route for the synthesis of phosphonate-containing siloxanes by the catalyst-free Kabachnik-Fields reaction

被引：0

作者：

Yang, Zhihui ^{[1
,2
,3
,4
]}

Wang, Xiaochen ^{[1
,2
,3
,4
]}

Wang, Yuanrong ^{[1
,2
,3
,4
]}

Yang, Jinyun ^{[1
,2
,3
,4
]}

Lu, Haifeng ^{[1
,2
,3
,4
]}

机构：

[1] Shandong Univ, Key Lab Special Funct Aggregated Mat, Jinan 250100, Shandong, Peoples R China

[2] Shandong Univ, Key Lab Colloid & Interface Chem Minist Educ, Jinan 250100, Shandong, Peoples R China

[3] Shandong Key Lab Adv Organosilicon Mat & Technol, Jinan, Shandong, Peoples R China

[4] Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Shandong, Peoples R China

来源：

RUSSIAN CHEMICAL BULLETIN | 2024年 / 73卷 / 09期

关键词：

siloxanes; amino phosphonates; catalyst-free reactions; Kabachnik-Fields reaction; organophosphorus compounds; organosilicon compounds; ONE-POT SYNTHESIS; ALPHA-AMINOPHOSPHONATES; ALDEHYDES;

D O I：

10.1007/s11172-024-4385-5

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new route for the synthesis of siloxanes containing substituents with the phosphonate and amino groups based on the catalyst-free Kabachnik-Fields reaction was developed. The synthesis was accomplished under mild conditions using 3-aminopropylsilanes, cyclic ketones, and diethyl phosphite as the starting materials to give the corresponding 1-(3-silylpropylamino)cycloalkylphosphonates in high yields.

引用

页码：2725 / 2729

页数：5

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