A novel route for the synthesis of phosphonate-containing siloxanes by the catalyst-free Kabachnik-Fields reaction

被引：0
|
作者：
Yang, Zhihui [1 ,2 ,3 ,4 ]
Wang, Xiaochen [1 ,2 ,3 ,4 ]
Wang, Yuanrong [1 ,2 ,3 ,4 ]
Yang, Jinyun [1 ,2 ,3 ,4 ]
Lu, Haifeng [1 ,2 ,3 ,4 ]
机构：
[1] Shandong Univ, Key Lab Special Funct Aggregated Mat, Jinan 250100, Shandong, Peoples R China
[2] Shandong Univ, Key Lab Colloid & Interface Chem Minist Educ, Jinan 250100, Shandong, Peoples R China
[3] Shandong Key Lab Adv Organosilicon Mat & Technol, Jinan, Shandong, Peoples R China
[4] Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Shandong, Peoples R China
来源：
RUSSIAN CHEMICAL BULLETIN | 2024年 / 73卷 / 09期
关键词：
siloxanes; amino phosphonates; catalyst-free reactions; Kabachnik-Fields reaction; organophosphorus compounds; organosilicon compounds; ONE-POT SYNTHESIS; ALPHA-AMINOPHOSPHONATES; ALDEHYDES;
D O I：
10.1007/s11172-024-4385-5
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new route for the synthesis of siloxanes containing substituents with the phosphonate and amino groups based on the catalyst-free Kabachnik-Fields reaction was developed. The synthesis was accomplished under mild conditions using 3-aminopropylsilanes, cyclic ketones, and diethyl phosphite as the starting materials to give the corresponding 1-(3-silylpropylamino)cycloalkylphosphonates in high yields.
引用
收藏
页码：2725 / 2729
页数：5
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