Catalyst-Support Interaction in Polyaniline-Supported Ni3Fe Oxide to Boost Oxygen Evolution Activities for Rechargeable Zn-Air Batteries

被引：6
|
作者：
Zou, Xiaohong [1 ]
Lu, Qian [2 ,3 ]
Tang, Mingcong [1 ]
Wu, Jie [1 ]
Zhang, Kouer [1 ]
Li, Wenzhi [1 ]
Hu, Yunxia [1 ]
Xu, Xiaomin [4 ]
Zhang, Xiao [1 ,5 ,6 ]
Shao, Zongping [4 ]
An, Liang [1 ,5 ,6 ]
机构：
[1] Hong Kong Polytech Univ, Dept Mech Engn, Hung Hom, Hong Kong, Peoples R China
[2] Nanjing Univ Informat Sci & Technol, Jiangsu Collaborat Innovat Ctr Atmospher Environm, Sch Environm Sci & Technol, Jiangsu Key Lab Atmospher Environm Monitoring & Po, Nanjing 210044, Peoples R China
[3] Chinese Univ Hong Kong, Dept Chem, Shatin, Ma Lin Bldg, Hong Kong 999077, Peoples R China
[4] Curtin Univ, WA Sch Mines Minerals Energy & Chem Engn WASM MECE, Perth, WA 6102, Australia
[5] Hong Kong Polytech Univ, Res Inst Adv Mfg, Hung Hom, Hong Kong, Peoples R China
[6] Hong Kong Polytech Univ, Res Inst Smart Energy, Hung Hom, Hong Kong, Peoples R China
来源：
NANO-MICRO LETTERS | 2025年 / 17卷 / 01期
基金：
中国国家自然科学基金;
关键词：
Catalyst-support interaction; Supported catalysts; Heterointerface; Oxygen evolution reaction; Zn-air batteries; CONDUCTIVE POLYMERS; ELECTROCATALYSTS; METAL; NANOSHEETS; REDUCTION; COMPOSITE;
D O I：
10.1007/s40820-024-01511-4
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Catalyst-support interaction plays a crucial role in improving the catalytic activity of oxygen evolution reaction (OER). Here we modulate the catalyst-support interaction in polyaniline-supported Ni3Fe oxide (Ni3Fe oxide/PANI) with a robust hetero-interface, which significantly improves oxygen evolution activities with an overpotential of 270 mV at 10 mA cm(-2) and specific activity of 2.08 mA cm(ECSA)(-2) at overpotential of 300 mV, 3.84-fold that of Ni3Fe oxide. It is revealed that the catalyst-support interaction between Ni3Fe oxide and PANI support enhances the Ni-O covalency via the interfacial Ni-N bond, thus promoting the charge and mass transfer on Ni3Fe oxide. Considering the excellent activity and stability, rechargeable Zn-air batteries with optimum Ni3Fe oxide/PANI are assembled, delivering a low charge voltage of 1.95 V to cycle for 400 h at 10 mA cm(-2). The regulation of the effect of catalyst-support interaction on catalytic activity provides new possibilities for the future design of highly efficient OER catalysts.
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页数：15
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