Compact Multigas Sensor Using Laser Absorption Spectroscopy Combined With the Spectral Matrix Compensation Method

被引:0
作者
Gao, Huifang [1 ]
Wang, Qianjin [2 ]
Lu, Yuangang [1 ]
Zhang, Zhirong [2 ,3 ]
机构
[1] Nanjing Univ Aeronaut & Astronaut, Coll Astronaut, Key Lab Space Photoelect Detect & Percept, Minist Ind & Informat Technol, Nanjing 211106, Peoples R China
[2] Chinese Acad Sci, Anhui Inst Opt & Fine Mech, Anhui Prov Key Lab Photon Devices & Mat, HFIPS, Hefei 230031, Anhui, Peoples R China
[3] Adv Laser Technol Lab Anhui Prov, Hefei 230037, Anhui, Peoples R China
基金
中国国家自然科学基金;
关键词
Silicon; Gases; Absorption; Optical sensors; Optical variables measurement; Gas lasers; Spectroscopy; Interference; Standards; Optical feedback; Aliasing spectral demodulation; multigas sensor; simultaneous detection; spectral matrix compensation (SMC) method; TEMPERATURE; H2O; N2O; CO;
D O I
10.1109/JSEN.2024.3498046
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Here, a compact multigas sensor using tunable diode laser absorption spectroscopy (TDLAS) combined with the spectral matrix compensation (SMC) method is developed. Each gas measurement unit, assisted with highly integrated circuits and a stable miniaturized gas multi pass cell, can effectively distinguish the types of industrial gases and conduct subsequent inspections. Compared with traditional time-division, frequency-division, and optical multiplexing techniques, this sensor avoids the interference introduced by hardware. Moreover, facing the common problem of mutual interference in gas measurement under complex conditions, a new SMC method is proposed to address the aliasing spectral demodulation of overlapping absorption lines. In a proof-of-concept experiment, the simultaneous detection of oxygen (O-2), methane (CH4), acetylene (C2H2), and carbon monoxide (CO) in a complex environment is realized successfully. The measurement results demonstrate that the limits of detection (LODs) of this sensor for O-2, CH4, C2H2, and CO are 0.14%, 0.86, 1.01, and 0.31 ppm, respectively, and the precisions for long-term measurement are 0.03%, 1.05, 0.05, and 0.08 ppm, respectively. Meanwhile, in the interference test, with the increase of CH4 concentration, the impact on 10-ppm CO becomes greater, but the fluctuation is no more than 0.6 ppm. In summary, this sensor can not only fulfill multigas measurement and aliasing spectral demodulation but also further expand the application prospects of TDLAS.
引用
收藏
页码:443 / 448
页数:6
相关论文
共 32 条
[1]   Greater focus needed on methane leakage from natural gas infrastructure [J].
Alvarez, Ramon A. ;
Pacala, Stephen W. ;
Winebrake, James J. ;
Chameides, William L. ;
Hamburg, Steven P. .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2012, 109 (17) :6435-6440
[2]   A trace CH4 detection system based on DAS calibrated WMS technique [J].
Dang, Jingmin ;
Zhang, Junhe ;
Dong, Xinju ;
Kong, Lijuan ;
Yu, Haiye .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2022, 266
[3]   A Laser-Based Multipass Absorption Sensor for Sub-ppm Detection of Methane, Acetylene and Ammonia [J].
Duan, Wei ;
Yan, Fuwu ;
Wang, Yu ;
Zhang, Hui ;
Ma, Liuhao ;
Wen, Daxin ;
Wang, Wei ;
Sheng, Gang ;
Wang, Qiang .
SENSORS, 2022, 22 (02)
[4]   The HITRAN2016 molecular spectroscopic database [J].
Gordon, I. E. ;
Rothman, L. S. ;
Hill, C. ;
Kochanov, R. V. ;
Tan, Y. ;
Bernath, P. F. ;
Birk, M. ;
Boudon, V. ;
Campargue, A. ;
Chance, K. V. ;
Drouin, B. J. ;
Flaud, J. -M. ;
Gamache, R. R. ;
Hodges, J. T. ;
Jacquemart, D. ;
Perevalov, V. I. ;
Perrin, A. ;
Shine, K. P. ;
Smith, M. -A. H. ;
Tennyson, J. ;
Toon, G. C. ;
Tran, H. ;
Tyuterev, V. G. ;
Barbe, A. ;
Csaszar, A. G. ;
Devi, V. M. ;
Furtenbacher, T. ;
Harrison, J. J. ;
Hartmann, J. -M. ;
Jolly, A. ;
Johnson, T. J. ;
Karman, T. ;
Kleiner, I. ;
Kyuberis, A. A. ;
Loos, J. ;
Lyulin, O. M. ;
Massie, S. T. ;
Mikhailenko, S. N. ;
Moazzen-Ahmadi, N. ;
Mueller, H. S. P. ;
Naumenko, O. V. ;
Nikitin, A. V. ;
Polyansky, O. L. ;
Rey, M. ;
Rotger, M. ;
Sharpe, S. W. ;
Sung, K. ;
Starikova, E. ;
Tashkun, S. A. ;
Vander Auwera, J. .
JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER, 2017, 203 :3-69
[5]   Open-path anti-pollution multi-pass cell-based TDLAS sensor for the online measurement of atmospheric H2O and CO2 fluxes [J].
Gu, Mingsi ;
Chen, Jiajin ;
Mei, Jiaoxu ;
Tan, Tu ;
Wang, Guishi ;
Liu, Kun ;
Liu, Gang ;
Gao, Xiaoming .
OPTICS EXPRESS, 2022, 30 (24) :43961-43972
[6]   Multiple Gases Detection Based on Periodical Mode-Locked Cavity-Enhanced Absorption Spectroscopy Using a Single-Mode Diode Laser [J].
He, Qixin ;
Zheng, Chuantao ;
Ye, Weilin ;
Tittel, Frank K. .
IEEE SENSORS JOURNAL, 2023, 23 (06) :5720-5725
[7]   Optical gas sensing: a review [J].
Hodgkinson, Jane ;
Tatam, Ralph P. .
MEASUREMENT SCIENCE AND TECHNOLOGY, 2013, 24 (01)
[8]   Simultaneous detection of multiple gases using multi-resonance photoacoustic spectroscopy [J].
Huang, Qi ;
Wei, Yuan ;
Li, Jingsong .
SENSORS AND ACTUATORS B-CHEMICAL, 2022, 369
[9]   Absorption spectroscopy based high-speed oxygen concentration measurements at elevated gas temperatures [J].
Jatana, Gurneesh S. ;
Perfetto, Anthony K. ;
Geckler, Samuel C. ;
Partridge, William P. .
SENSORS AND ACTUATORS B-CHEMICAL, 2019, 293 :173-182
[10]   Coal mine methane: A review of capture and utilization practices with benefits to mining safety and to greenhouse gas reduction [J].
Karacan, C. Oezgen ;
Ruiz, Felicia A. ;
Cote, Michael ;
Phipps, Sally .
INTERNATIONAL JOURNAL OF COAL GEOLOGY, 2011, 86 (2-3) :121-156