Synthesis and Structure of Manganese Complexes with N,N'-bis[(2,4,6-trimethylphenyl)imino]acenaphthene

被引：2

作者：

Laricheva, Yu. A. ^{[1
]}

Guan, Ch. ^{[2
]}

Kuratieva, N. V. ^{[1
]}

Romashev, N. F. ^{[1
]}

Gushchin, A. L. ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk, Russia

[2] Novosibirsk Natl Res State Univ, Novosibirsk, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2024年 / 50卷 / 09期

关键词：

complexes; manganese; bis(imino)acenaphthenes (BIANs); synthesis; X-ray diffraction; quantum chemical calculations; BIAN LIGANDS SYNTHESIS; COPPER(II) COMPLEXES; CRYSTAL-STRUCTURES; METAL; MN(II); REDUCTION; OXIDATION; EMISSION;

D O I：

10.1134/S1070328424600578

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Methods for the synthesis of new manganese(II) complexes with N,N'-bis[(2,4,6-trimethylphenyl)iminoacenaphthene (Tmp-bian), [Mn(Tmp-bian)Br-2] (I), [Mn(Tmp-bian)(EtOH)Br-2] (Ia), [Mn(Tmp-bian)Cl-2] (II), [Mn(Tmp-bian)(2)(ClO4)(2)] (III), and [Mn(Tmp-bian)(2)(OTs)(2)] (IV) were developed. The obtained compounds were characterized by elemental analysis and IR spectroscopy. The molecular structures of I, Ia, and III were determined by X-ray diffraction (CCDC nos. 233510-233512). The electronic structures of I and III were established by quantum chemical calculations using density functional theory (DFT).

引用

页码：662 / 672

页数：11

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