Development of glass sealants for proton conducting ceramic cells: materials, concepts and challenges

被引：2

作者：

Georgolamprou, Xanthi ^{[1
]}

Ritucci, Ilaria ^{[1
,2
]}

Pirou, Steven ^{[1
,2
]}

Kiebach, Ragnar ^{[1
]}

机构：

[1] Tech Univ Denmark, Dept Energy Convers & Storage, Anker Engelunds Vej, DK-2800 Lyngby, Denmark

[2] Topsoe A S, Haldor Topsoes Alle 1, DK-2800 Lyngby, Denmark

来源：

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ENGINEERING | 2024年 / 19卷 / 01期

关键词：

Proton conducting ceramics; Sealing; Gas separation membranes; Glass; Glass ceramics; HIGH-PERFORMANCE; FUEL-CELLS; ELECTROLYSIS CELLS; MANUFACTURING COST; NEXT-GENERATION; HYDROGEN; TECHNOLOGY; CATHODE; METHANE; STACKS;

D O I：

10.1186/s40712-024-00184-6

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

In this study, we have successfully developed and tested sealing concepts for symmetrical, planar proton-conducting ceramic cells (PCCCs). Three glass sealants from the field of solid oxide cells were investigated as potential compatible sealing materials for PCCCs. The most promising results were obtained with a SiO2-MgO-CaO-Na2O-Al2O3-ZrO2-B2O3 glass, which provided a dense, crack-free sealant between the proton-conducting ceramic cells and the Al2O3-coated ferritic steels. During the sealing process, a reaction layer between the interface of the BaCe0.2Zr0.7Y0.1O3-delta contained in the PCCCs and the glass-ceramic, occurred. Here, we propose a reaction mechanism for this interaction and discuss its impact on potential applications. Moreover, next to evaluating potential glass sealants, we have successfully designed and demonstrated a new sealing geometry that prevents a potential gas crossover in the symmetrical proton-conducting ceramic cell.

引用

页数：12

共 51 条

[1] Commercial alkaline earth boroaluminosilicate glasses for sealing solid oxide cell stacks. Part I: Development of glass-ceramic microstructure and thermomechanical properties [J].

Agersted, Karsten ;

Balic-Zunic, Tonci .

INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY, 2018, 15 (02) :255-266

[2] Comprehensive Analysis of Sorption Enhanced Steam Methane Reforming in a Variable Volume Membrane Reactor [J].

Anderson, David M. ;

Yun, Thomas M. ;

Kottke, Peter A. ;

Fedorov, Andrei G. .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2017, 56 (07) :1758-1771

[3] Characterization and testing of glass-ceramic sealants for protonic ceramic electrolysis cells applications [J].

Anelli, S. ;

Baggio, A. ;

Ferrero, D. ;

Schmider, D. ;

Dailly, J. ;

Santarelli, M. ;

Smeacetto, F. .

CERAMICS INTERNATIONAL, 2024, 50 (10) :17520-17531

[4] Characterization of ionic transport through BaCe0.2 Zr0.7Y0.1O3-δ membranes in galvanic and electrolytic operation [J].

Babiniec, Sean M. ;

Ricote, Sandrine ;

Sullivan, Neal P. .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2015, 40 (30) :9278-9286

[5] Thermo-fluid dynamics modelling of steam electrolysis in fully-assembled tubular high-temperature proton-conducting cells [J].

Catalan-Martinez, D. ;

Navarrete, L. ;

Tarach, M. ;

Santos-Blasco, J. ;

Vollestad, E. ;

Norby, T. ;

Budd, M., I ;

Veenstra, P. ;

Serra, J. M. .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2022, 47 (65) :27787-27799

[6]

Chou YS., 2014, Pacific Northwest National Lab, DOI [10.2172/1171902, DOI 10.2172/1171902]

[7] Single-step hydrogen production from NH3, CH4, and biogas in stacked proton ceramic reactors [J].

Clark, Daniel ;

Malerod-Fjeld, Harald ;

Budd, Michael ;

Yuste-Tirados, Irene ;

Beeaff, Dustin ;

Aamodt, Simen ;

Nguyen, Kevin ;

Ansaloni, Luca ;

Peters, Thijs ;

Vestre, Per K. ;

Pappas, Dimitrios K. ;

Valls, Maria, I ;

Remiro-Buenamanana, Sonia ;

Norby, Truls ;

Bjorheim, Tor S. ;

Serra, Jose M. ;

Kjolseth, Christian .

SCIENCE, 2022, 376 (6591) :390-+

[8] BCY-based proton conducting ceramic cell: 1000 h of long term testing in fuel cell application [J].

Dailly, J. ;

Marrony, M. .

JOURNAL OF POWER SOURCES, 2013, 240 :323-327

[9] Fabrication of multi-layered structures for proton conducting ceramic cells [J].

Deibert, Wendelin ;

Ivanova, Mariya E. ;

Huang, Yuanye ;

Merkle, Rotraut ;

Maier, Joachim ;

Meulenberg, Wilhelm A. .

JOURNAL OF MATERIALS CHEMISTRY A, 2022, 10 (05) :2362-2373

[10] Proton-conducting oxides for energy conversion and storage [J].

Duan, Chuancheng ;

Huang, Jake ;

Sullivan, Neal ;

O'Hayre, Ryan .

APPLIED PHYSICS REVIEWS, 2020, 7 (01)

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