Poly(lactic acid) (PLA)/micro-fibrillated cellulose (MFC) biocomposites for film blowing applications

被引:1
作者
Aliotta, Laura [1 ,2 ]
Gigante, Vito [1 ,2 ]
Garofalo, Giordano [3 ]
Baiamonte, Marilena [3 ]
Molinari, Giovanna [1 ,2 ,4 ]
Lazzeri, Andrea [1 ,2 ]
La Mantia, Francesco Paolo [2 ,3 ]
Botta, Luigi [2 ,3 ]
机构
[1] Univ Pisa, Dept Civil & Ind Engn, L Go L Lazzarino 1, I-56122 Pisa, Italy
[2] Interuniv Natl Consortium Mat Sci & Technol INSTM, Via Giusti 9, I-50121 Florence, Italy
[3] Univ Palermo, Dept Engn, Viale Sci, I-90128 Palermo, Italy
[4] Ist Italiano Tecnol, Ctr Mat Interfaces, Electron Crystallog, I-56025 Pontedera, Italy
关键词
Biocomposites; Film blowing; Morphology; Elongational flow; ELONGATIONAL FLOW; CRYSTALLIZATION KINETICS; MECHANICAL-PROPERTIES; RHEOLOGICAL BEHAVIOR; PLA; BARRIER; PLASTICIZERS; POLYLACTIDES; MORPHOLOGY; BLENDS;
D O I
10.1007/s10570-024-06309-6
中图分类号
TB3 [工程材料学]; TS [轻工业、手工业、生活服务业];
学科分类号
0805 ; 080502 ; 0822 ;
摘要
Film blowing is one of the most widely used structuring processes to produce thin polymer films. During this process, unique morphologies are induced in polymer-filled composites by elongational flow. In this work, the effect of the presence of micro fibrillated cellulose (MFC) on the morphology and mechanical properties of poly (lactic acid) (PLA)/MFC biocomposites subjected to non-isothermal elongation flow in a melt spinning operation was evaluated to assess the filmability of the proposed formulations and the final morphology achieved during film blowing. The produced films were characterized to determine how the achieved morphology affected the thermal, optical, barrier, and mechanical properties of the films, paying particular attention on the improvements achieved thanks to the MFC addition.
引用
收藏
页码:965 / 981
页数:17
相关论文
共 58 条
[1]   Natural-based plasticizers and biopolymer films: A review [J].
Adeodato Vieira, Melissa Gurgel ;
da Silva, Mariana Altenhofen ;
dos Santos, Lucielen Oliveira ;
Beppu, Marisa Masumi .
EUROPEAN POLYMER JOURNAL, 2011, 47 (03) :254-263
[2]   Developments of biobased plasticizers for compostable polymers in the green packaging applications: A review [J].
Alhanish, Atika ;
Abu Ghalia, Mustafa .
BIOTECHNOLOGY PROGRESS, 2021, 37 (06)
[3]   Effect of biobased plasticizers, used as dispersing aids, on mechanical, rheological and thermal properties of micro fibrillated cellulose (MFC)/poly (lactic acid) (PLA) biocomposites over the time: how MFC controls the plasticizer migration? [J].
Aliotta, Laura ;
Gigante, Vito ;
Molinari, Giovanna ;
D'Ambrosio, Roberto ;
Botta, Luigi ;
La Mantia, Francesco Paolo ;
Lazzeri, Andrea .
CELLULOSE, 2023, 30 (04) :2237-2252
[4]   Study on the preferential distribution of acetyl tributyl citrate in poly (lactic) acid-poly(butylene adipate-co-terephthalate) blends [J].
Aliotta, Laura ;
Canesi, Ilaria ;
Lazzeri, Andrea .
POLYMER TESTING, 2021, 98
[5]   Poly(lactic acid) (PLA)/poly(butylene succinate adipate) (PBSA) films with Micro fibrillated cellulose (MFC) and cardanol for packaging applications [J].
Apicella, Annalisa ;
Molinari, Giovanna ;
Gigante, Vito ;
Pietrosanto, Arianna ;
Incarnato, Loredana ;
Aliotta, Laura ;
Lazzeri, Andrea .
CELLULOSE, 2024, 31 (15) :9173-9190
[6]   Characterization of PLA-limonene blends for food packaging applications [J].
Arrieta, Marina P. ;
Lopez, Juan ;
Ferrandiz, Santiago ;
Peltzer, Mercedes A. .
POLYMER TESTING, 2013, 32 (04) :760-768
[7]   Effect of the Elongational Flow on the Morphology and Properties of Polymer Systems: A Brief Review [J].
Arrigo, Rossella ;
Malucelli, Giulio ;
La Mantia, Francesco Paolo .
POLYMERS, 2021, 13 (20)
[8]   An overview of polylactides as packaging materials [J].
Auras, R ;
Harte, B ;
Selke, S .
MACROMOLECULAR BIOSCIENCE, 2004, 4 (09) :835-864
[9]   Cast extrusion of low gas permeability bioplastic sheets in PLA/PBS and PLA/PHB binary blends [J].
Aversa, C. ;
Barletta, M. ;
Puopolo, M. ;
Vesco, S. .
POLYMER-PLASTICS TECHNOLOGY AND MATERIALS, 2020, 59 (03) :231-240
[10]   Characterization of poly(lactic acid) biocomposites filled with chestnut shell waste [J].
Barczewski, M. ;
Matykiewicz, D. ;
Krygier, A. ;
Andrzejewski, J. ;
Skorczewska, K. .
JOURNAL OF MATERIAL CYCLES AND WASTE MANAGEMENT, 2018, 20 (02) :914-924