Synthesis of new class of trithiadiazacycloalkane 1,1-dioxides using Yb(Sm)-contaning catalysts and conformational analysis of the macroheterocycles

被引：0
作者：
Khairullina, Regina R. [1 ]
Tyumkina, Tatyana V. [1 ]
机构：
[1] Russian Acad Sci, Inst Petrochemistry & Catalysis, 141 Oktyabrya Ave, Ufa 450075, Russia
来源：
CHEMISTRY OF HETEROCYCLIC COMPOUNDS | 2024年
关键词：
1,6(7,8,9,10,13)-bishydroxy-2,5(6,7,8,9,12)-dithioalkanes; alpha; omega-dithiols; macrohetero[N; S]cyclic compounds; 1,3,6(7)-oxadithioalkanes; sulfamide; catalysis; cyclothiomethylation; MULTICOMPONENT REACTIONS; MACROCYCLES; DERIVATIVES; CH2O;
D O I：
10.1007/s10593-024-03353-9
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An effective method has been developed for the synthesis of unique macrohetero[N,S]cycles 1,4,7(8,9,10,11,12,14)-trithia-2,9(10,11,12,13,14,16)-diazacycloalkane 1,1-dioxides by cyclothiomethylation of sulfonamide with bishydroxydithioalkanes and 1,3,6(7)-oxadithioalkanes in the presence of rare earth metal catalysts. A detailed conformational analysis of 1,4,7-trithia-2,9-diazacycloalkane 1,1-dioxide has been carried out, and the energetically most probable path of cyclic interconversion has been proposed.
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收藏
页码：409 / 414
页数：6
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