Facile synthesis of PVP surfactant-aided MoO3/g-C3N4 nanocomposites improves the performance of photocatalytic dye degradation and electrocatalytic overall water-splitting bustle

被引:0
作者
Vasanthi, G. [1 ]
Dharani, P. [1 ]
Prabhuraj, T. [1 ]
Gomathi, A. [1 ]
Kumar, K. A. Ramesh [2 ]
Maadeswaran, P. [1 ,3 ]
机构
[1] Periyar Univ, Dept Energy Sci & Technol, Adv Nanomat & Energy Res Lab, Salem, Tamil Nadu, India
[2] Periyar Univ, Dept Energy Sci & Technol, Adv Bioenergy & Biofuels Res Lab, Salem, Tamil Nadu, India
[3] Periyar Univ, Ctr Instrumentat & Maintenance Facil, Salem, Tamil Nadu, India
关键词
CARBON NITRIDE; BIFUNCTIONAL ELECTROCATALYST; HYDROTHERMAL SYNTHESIS; HIGHLY EFFICIENT; HETEROJUNCTION; PHOTOANODE; EVOLUTION; G-C3N4; MORPHOLOGY; FILM;
D O I
10.1007/s10854-024-13962-x
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
This work describes the MoO3/g-C3N4 nanocomposite that has been synthesized via a hydrothermal process and it demonstrates a potential application designed for photocatalytic RhB dye degradation and electrocatalytic overall water splitting. Hence the XRD, FT-IR, UV-DRS, SEM, TEM and XPS characterized the functional electrode's morphological, optical, and structural characteristics. These techniques revealed that the g-C3N4 surfaces were effectively MoO3 nanocrystals without any other unwanted species formation. The MoO3/g-C3N4 nanocomposite demonstrates superior photocatalytic RhB dye degradation under alternating sunlight irradiation up to 88% for 60 min. The Electrocatalytic overall water-splitting performance is evaluated by LSV, chronoamperometry, chronopotentiometry, and EIS analysis which exhibit higher current density, good stability, low overpotential, and small Tafel slop of the MoO3/g-C3N4 nanocomposite than bare MoO3 catalyst.
引用
收藏
页数:13
相关论文
共 67 条
[31]   Construction of g-C3N4/BCN two-dimensional heterojunction photoanode for enhanced photoelectrochemical water splitting [J].
Lei, Nan ;
Li, Junqi ;
Song, Qianqian ;
Liang, Zheng .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2019, 44 (21) :10498-10507
[32]   A g-C3N4/WO3 photoanode with exceptional ability for photoelectrochemical water splitting [J].
Li, Haibo ;
Zhao, Fengyi ;
Zhang, Jincheng ;
Luo, Lei ;
Xiao, Xujing ;
Huang, Yongchao ;
Ji, Hongbing ;
Tong, Yexiang .
MATERIALS CHEMISTRY FRONTIERS, 2017, 1 (02) :338-342
[33]   Highly enhanced H2 evolution of MoO3/g-C3N4 hybrid composites based on a direct Z-scheme photocatalytic system [J].
Li, Kunqiao ;
Wu, Wanbao ;
Jiang, Yanqiu ;
Wang, Zhe ;
Liu, Xing ;
Li, Junzhuo ;
Xia, Debin ;
Xu, Xianzhu ;
Fan, Jizhuang ;
Lin, Kaifeng .
INORGANIC CHEMISTRY FRONTIERS, 2021, 8 (05) :1154-1165
[34]   Effective photocatalytic H2O2 production under visible light irradiation at g-C3N4 modulated by carbon vacancies [J].
Li, Shuna ;
Dong, Guohui ;
Hailili, Reshalaiti ;
Yang, Liping ;
Li, Yingxuan ;
Wang, Fu ;
Zeng, Yubin ;
Wang, Chuanyi .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2016, 190 :26-35
[35]   Preparation and characterization of graphitic carbon nitride through pyrolysis of melamine [J].
Li, Xuefei ;
Zhang, Jian ;
Shen, Longhai ;
Ma, Yanmei ;
Lei, Weiwei ;
Cui, Qiliang ;
Zou, Guangtian .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2009, 94 (02) :387-392
[36]   Heterostructured MoO2@MoS2@Co9S8 nanorods as high efficiency bifunctional electrocatalyst for overall water splitting [J].
Li, Yanqiang ;
Wang, Chao ;
Cui, Ming ;
Xiong, Jiabin ;
Mi, Liwei ;
Chen, Siru .
APPLIED SURFACE SCIENCE, 2021, 543
[37]   Visible-light-induced blue MoO3-C3N4 composite with enhanced photocatalytic activity [J].
Li, Yeping ;
Huang, Liying ;
Xu, Jingbo ;
Xu, Hui ;
Xu, Yuanguo ;
Xia, Jixiang ;
Li, Huaming .
MATERIALS RESEARCH BULLETIN, 2015, 70 :500-505
[38]   Synthesis and characterization of microporous carbon nitride [J].
Liu, Lin ;
Ma, Ding ;
Zheng, Heng ;
Li, Xiujie ;
Cheng, Mojie ;
Bao, Xinhe .
MICROPOROUS AND MESOPOROUS MATERIALS, 2008, 110 (2-3) :216-222
[39]   13.8% Efficiency Hybrid Si/Organic Heterojunction Solar Cells with MoO3 Film as Antireflection and Inversion Induced Layer [J].
Liu, Ruiyuan ;
Lee, Shuit-Tong ;
Sun, Baoquan .
ADVANCED MATERIALS, 2014, 26 (34) :6007-+
[40]   Novel framework g-C3N4 film as efficient photoanode for photoelectrochemical water splitting [J].
Lu, Xue ;
Liu, Zhifeng ;
Li, Junwei ;
Zhang, Jing ;
Guo, Zhengang .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2017, 209 :657-662