Extraction of americium, curium, and californium with LN resin from HCl and HNO3

被引:1
|
作者
Kmak, Kelly N. [1 ]
Despotopulos, John D. [1 ]
Ahrens, Nicole [1 ,2 ]
Hoffman, Derek R. [1 ]
Kerlin, William M. [1 ]
机构
[1] Lawrence Livermore Natl Lab, Nucl & Chem Sci Div, Livermore, CA 94550 USA
[2] Colorado State Univ, Environm & Radiol Hlth Sci, Ft Collins, CO USA
关键词
Extraction chromatography; Americium; Curium; Californium; SOLVENT-EXTRACTION; CHROMATOGRAPHY; SEPARATION; URANIUM; BERKELIUM; ACTINIDE; ELEMENTS; COLUMNS; ACID;
D O I
10.1007/s10967-024-09799-7
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The uptake of Am-241, Cm-244 and Cf-249 with LN resin was studied in HCl and HNO3 solutions with concentrations ranging from 0.02 to 2.5 M. There is high uptake at concentrations < 0.1 M in both acids for all three isotopes with decreasing uptake at higher concentrations and negligible extraction at >= 0.6 M. Californium has a higher extraction than americium and curium, which are extremely similar. Kinetics studies showed rapid uptake of all three isotopes. Column studies were performed to demonstrate the separation of Am-241 and Cf-249, and a bulk separation including nine stable lanthanides along with Am-241, Cf-249, and Y-88.
引用
收藏
页码:575 / 582
页数:8
相关论文
共 50 条
  • [1] Extraction of gold, mercury, and lead with TEVA resin from HCl and HNO3
    Kmak, Kelly N.
    Despotopulos, John D.
    JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2022, 331 (05) : 2227 - 2233
  • [2] Extraction of gold, mercury, and lead with TEVA resin from HCl and HNO3
    Kelly N. Kmak
    John D. Despotopulos
    Journal of Radioanalytical and Nuclear Chemistry, 2022, 331 : 2227 - 2233
  • [3] SEPARATION OF AMERICIUM (CURIUM), BERKELIUM AND CALIFORNIUM BY EXTRACTION CHROMATOGRAPHY
    KOOI, J
    BODEN, R
    WIJKSTRA, J
    JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1964, 26 (12): : 2300 - 2302
  • [4] Extraction of trivalent americium and europium with TODGA homologs from HNO3 solution
    Wang, Zhipeng
    Huang, Huang
    Ding, Songdong
    Hu, Xiaoyang
    Zhang, Lirong
    Liu, Ying
    Song, Lianjun
    Chen, Zhili
    Li, Shimeng
    JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2017, 313 (02) : 309 - 318
  • [5] Extraction of trivalent americium and europium with TODGA homologs from HNO3 solution
    Zhipeng Wang
    Huang Huang
    Songdong Ding
    Xiaoyang Hu
    Lirong Zhang
    Ying Liu
    Lianjun Song
    Zhili Chen
    Shimeng Li
    Journal of Radioanalytical and Nuclear Chemistry, 2017, 313 : 309 - 318
  • [6] DENITRATION OF HNO3 HCL MIXTURES
    HOLZE, K
    WIECZOREK, H
    DECKWER, WD
    CHEMIE INGENIEUR TECHNIK, 1984, 56 (01) : 56 - 58
  • [7] Extraction of 197mHg with TIBPS in HNO3 and HCl media
    Kelly N. Kmak
    Carlos A. Valdez
    Deon S. Anex
    John D. Despotopulos
    Journal of Radioanalytical and Nuclear Chemistry, 2022, 331 : 1629 - 1634
  • [8] CALCULATION OF HCL AND HNO3 EXTRACTION ISOTHERMS BY BENZENE AND ORTHO XYLENE
    BOBYLEV, AP
    KOMISSAR.LN
    ZHURNAL FIZICHESKOI KHIMII, 1974, 48 (01): : 145 - 148
  • [9] THERMODYNAMICS OF DINONYLNAPHTHALENE SULFONIC-ACID (HD) - EXTRACTION OF TRIVALENT AMERICIUM, CURIUM AND CALIFORNIUM
    RAIEH, MA
    ALY, HF
    JOURNAL OF RADIOANALYTICAL CHEMISTRY, 1980, 57 (01): : 17 - 21
  • [10] Effects of HNO3 concentration on the pit morphologies of aluminum foil etched in HNO3–HCl and HNO3–H2SO4–HCl solutions
    Quan-xiu Yi
    Ye-dong He
    Ning Peng
    Hong-zhou Song
    Xiao-fei Yang
    Xiao-yu Cai
    InternationalJournalofMineralsMetallurgyandMaterials, 2016, 23 (01) : 70 - 76