共 59 条
Impact in continuous flow heated mechanochemical technology: An improved solketal synthesis
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作者:

Nguyen, Remi
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Deasyl SA, 109 Chemin du pont du centenaire,1228 Plan Les Oua, CH-1228 Geneva, Switzerland
PSL Res Univ, Inst Chem Life & Hlth Sci, Chim ParisTech, CNRS, 11 rue Pierre & Marie Curie, F-75005 Paris, France Deasyl SA, 109 Chemin du pont du centenaire,1228 Plan Les Oua, CH-1228 Geneva, Switzerland

Haloumi, Samy
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Deasyl SA, 109 Chemin du pont du centenaire,1228 Plan Les Oua, CH-1228 Geneva, Switzerland Deasyl SA, 109 Chemin du pont du centenaire,1228 Plan Les Oua, CH-1228 Geneva, Switzerland

Malpartida, Irene
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Deasyl SA, 109 Chemin du pont du centenaire,1228 Plan Les Oua, CH-1228 Geneva, Switzerland Deasyl SA, 109 Chemin du pont du centenaire,1228 Plan Les Oua, CH-1228 Geneva, Switzerland

Len, Christophe
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PSL Res Univ, Inst Chem Life & Hlth Sci, Chim ParisTech, CNRS, 11 rue Pierre & Marie Curie, F-75005 Paris, France
Univ Technol Compiegne, F-60200 Compiegne, France Deasyl SA, 109 Chemin du pont du centenaire,1228 Plan Les Oua, CH-1228 Geneva, Switzerland
机构:
[1] Deasyl SA, 109 Chemin du pont du centenaire,1228 Plan Les Oua, CH-1228 Geneva, Switzerland
[2] PSL Res Univ, Inst Chem Life & Hlth Sci, Chim ParisTech, CNRS, 11 rue Pierre & Marie Curie, F-75005 Paris, France
[3] Univ Technol Compiegne, F-60200 Compiegne, France
关键词:
Mechanochemistry;
Continuous flow;
Glycerol;
Solketal;
Homogeneous catalysis;
BIODIESEL PRODUCTION;
FUEL ADDITIVES;
GLYCEROL;
ACETALIZATION;
CONVERSION;
CATALYSTS;
ACETONE;
ACETAL;
HYDROGENATION;
KETALIZATION;
D O I:
10.1007/s41981-024-00339-8
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Impact in Continuous flow Heated Mechanochemistry (ICHEM) was used for the production of solketal at 60 degrees C using glycerol and acetone in the presence of homogeneous FeCl3.6H2O (1 mol%). In our optimized conditions, the target compound was obtained in 96% yield (conversion of 97% and selectivity of 99%) with a productivity of 276 g day-1 with a 80 mL continuous flow reactor. This new technology combines beads mechanochemistry and continuous flow and offers: (i) a better mixing of the two unsoluble parts (glycerol and acetone) by reducing the viscosity of the feed stream and (ii) an alternative of the single-screw and double-screw extruders which are unefficient with a liquid reaction media.
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页码:1 / 9
页数:9
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