Exploring ferroelectric and ferromagnetism properties of KNbO3-Fe2O3-V2O5-B2O3 glass for energy storage applications

被引:0
作者
Ali, A. M. [1 ]
Harby, Amany E. [1 ]
Hannora, Ahmed E. [2 ]
El-Desoky, M. M. [1 ]
机构
[1] Suez Univ, Fac Sci, Dept Phys, Suez 43518, Egypt
[2] Suez Univ, Fac Petr & Min Engn, Dept Sci & Engn Math, Suez 43518, Egypt
关键词
Glass; XRD; HRTEM; Ferroelectric; Energy storage applications; CO-DOPED KNBO3; ELECTRICAL-PROPERTIES; MAGNETIC-PROPERTIES; ROOM-TEMPERATURE; OPTICAL-PROPERTIES; CERAMICS; CRYSTALLIZATION; CONDUCTIVITY; PEROVSKITE; GRAPHENE;
D O I
10.1016/j.jallcom.2025.178996
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
10KNbO3-10Fe2O3-30V2O5-50B2O3glass was created using the conventional melt-quench technique. The formation of as-quenched sample has been investigated via X-ray diffraction)XRD( as well as HR-TEM (referred to as high resolution-transmission electron microscopy). sample's conductivity as well as dielectric properties were evaluated as a function of (f) frequency (0.5-1000 kHz) and temperature (289 K-424 K). 3-ferroelectric phase transitions are detected above ambient temperature, as indicated by the epsilon'-T measurements. The as-quenched sample has a significant dielectric constant (epsilon' - 16000 at 0.5 kHz) obtained at third Tc - 398 K (Curie temperature), this is related to phase transition in structure. The dielectric features of relaxor ferroelectric are studied. The behavior of a semi-conductor has been shown by ac conductivity's temperature-dependent variation. CBH model, correlated barrier hopping analyzes the temperature-dependence of parameter s as well as the ac conductivity. Binding energy (Wm) was calculated. The as-quenched sample's current-voltage (I-V) graph was measured. For an as-quenched sample, a memristor's pinched hysteresis loop is illustrated. The P-E hysteresis loops confirm that as-quenched sample was ferroelectric material. The hysteresis loops were used to estimate energy storage efficiency and density. The magnetic properties for as-quenched sample were characterized via vibrating sample magnetometer, VSM. Based on these results, we could predict that the as-quenched sample will be useful for both developing energy storage and future non-volatile memristor device applications.
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页数:10
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