Synthesis and Structure of Water-Soluble Complexes of Copper Fumarate and Succinate with Monoethanolamine

被引：0

作者：

Petrov, B. I. ^{[1
]}

Semenov, V. V. ^{[1
]}

Lazarev, N. M. ^{[1
]}

Baranov, E. V. ^{[1
]}

Lopatin, M. A. ^{[1
]}

机构：

[1] Russian Acad Sci, Razuvaev Inst Organometall Chem, Nizhnii Novgorod, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2024年 / 50卷 / 11期

关键词：

copper succinate; copper fumarate; monoethanolamine; X-ray diffraction; UV-Vis spectrum; solubility; CRYSTAL-STRUCTURE; THERMAL-DECOMPOSITION; MOLECULAR-STRUCTURES; THERMOLYSIS; MALEATE; ACID;

D O I：

10.1134/S1070328424600785

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

AbstractNew water-soluble copper(II) complexes with dicarboxylic acids were obtained by the heterogeneous reaction of copper hydroxy carbonate with succinic or fumaric acid in water at 50 degrees C. The additional introduction of monoethanolamine (MEA) into the complexes ensured high solubility of copper succinate and fumarate. The structures of the complexes [Cu(Suc)<middle dot>2MEA]<middle dot>H2O and [Cu(Fum)<middle dot>2MEA]<middle dot>H2O were studied by X-ray diffraction (CCDC nos. 2352578 and 2352579, respectively). The compounds were found to have a polymeric structure composed of zigzag chains.

引用

页码：936 / 944

页数：9

共 50 条

[1] Synthesis of water-soluble copper(II) complexes for the oxidation of catechol
Gichinga, Moses G.
Cooper, Brennan W.
Striegler, Susanne
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
[2] Synthesis of water-soluble polysulfo(octaphenyltetraazaporphyrin) complexes of cobalt and copper
Nemykin, V.N.
Chernij, V.Y.
Volkov, S.V.
Ukrainskij Khimicheskij Zhurnal, 2001, 67 (9-10): : 3 - 6
[3] Water-soluble Bis(thiosemicarbazonato)copper(II) Complexes
Buncic, Gojko
Hickey, James L.
Schieber, Christine
White, Jonathan M.
Crouch, Peter J.
White, Anthony R.
Xiao, Zhiguang
Wedd, Anthony G.
Donnelly, Paul S.
AUSTRALIAN JOURNAL OF CHEMISTRY, 2011, 64 (03) : 244 - 252
[4] Water-soluble organometallic complexes. Synthesis of water-soluble derivatives of cyclopentadienyl ligands
Schut, DM
Weakley, TJR
Tyler, DR
NEW JOURNAL OF CHEMISTRY, 1996, 20 (01) : 113 - 120
[5] STRUCTURE OF NONSTOICHIOMETRIC WATER-SOLUBLE POLYELECTROLYTE COMPLEXES
KHARENKO, OA
KHARENKO, AV
KASAIKIN, VA
ZEZIN, AB
KABANOV, VA
VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1979, 21 (12): : 2726 - 2733
[6] Synthesis of two novel copper water-soluble porphyrins
Skaug, BA
Bradshaw, JE
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 227 : U473 - U473
[7] Water-soluble copper pyrithione complexes with cytotoxic and antibacterial activity
Mishra, Atreyee
Djoko, Karrera Y.
Lee, Yi-Hsuan
Lord, Rianne M.
Kaul, Grace
Akhir, Abdul
Saxena, Deepanshi
Chopra, Sidharth
Walton, James W.
ORGANIC & BIOMOLECULAR CHEMISTRY, 2023, 21 (12) : 2539 - 2544
[8] Water-soluble Au(I) complexes, their synthesis and applications
Hristova, Yana R.
Kemper, Benedict
Besenius, Pol
TETRAHEDRON, 2013, 69 (49) : 10525 - 10533
[9] Synthesis and reactions of water-soluble diorganoplatinum(II) complexes
Komiya, S
Ikuine, M
Komine, N
Hirano, M
CHEMISTRY LETTERS, 2002, (01) : 72 - 73
[10] Synthesis and β-hydrogen elimination of water-soluble dialkylplatinum(II) complexes in water
Komiya, S
Ikuine, M
Komine, N
Hirano, M
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2003, 76 (01) : 183 - 188

← 1 2 3 4 5 →