Synthesis and Structure of Water-Soluble Complexes of Copper Fumarate and Succinate with Monoethanolamine

被引：0

作者：

Petrov, B. I. ^{[1
]}

Semenov, V. V. ^{[1
]}

Lazarev, N. M. ^{[1
]}

Baranov, E. V. ^{[1
]}

Lopatin, M. A. ^{[1
]}

机构：

[1] Russian Acad Sci, Razuvaev Inst Organometall Chem, Nizhnii Novgorod, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2024年 / 50卷 / 11期

关键词：

copper succinate; copper fumarate; monoethanolamine; X-ray diffraction; UV-Vis spectrum; solubility; CRYSTAL-STRUCTURE; THERMAL-DECOMPOSITION; MOLECULAR-STRUCTURES; THERMOLYSIS; MALEATE; ACID;

D O I：

10.1134/S1070328424600785

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

AbstractNew water-soluble copper(II) complexes with dicarboxylic acids were obtained by the heterogeneous reaction of copper hydroxy carbonate with succinic or fumaric acid in water at 50 degrees C. The additional introduction of monoethanolamine (MEA) into the complexes ensured high solubility of copper succinate and fumarate. The structures of the complexes [Cu(Suc)<middle dot>2MEA]<middle dot>H2O and [Cu(Fum)<middle dot>2MEA]<middle dot>H2O were studied by X-ray diffraction (CCDC nos. 2352578 and 2352579, respectively). The compounds were found to have a polymeric structure composed of zigzag chains.

引用

页码：936 / 944

页数：9

共 31 条

[1] O'Connor B.H., Maslen E.N., Acta Crystallogr, 20, (1966)
[2] Bassi P.S., Chopra G.S., Gupta B.R., Thermochim. Acta, 124, (1988)
[3] Ghoshal D., Ghosh A.K., Mostufa G., Inorg. Chim. Acta, 360, (2007)
[4] Caires F.J., Lima L.S., Carvalho C.T., Thermochim. Acta, 500, (2010)
[5] Yudanova L.I., Logvinenko V.A., Yudanov N.F., Inorg. Mater, 50, (2014)
[6] Carr N.J., Galwey A.K., J. Chem. Soc., Faraday Trans, 84, (1988)
[7] Inoue M., Kawaji H., Tojo T., Thermochim. Acta, 431, (2005)
[8] Ying M., Yang G., Xu Y., Analyst, 147, (2022)
[9] Prout C.K., Carruthers J.R., Rossotti F.J.C., J. Chem. Soc. A, (1971)
[10] Sobel S., Haigney A., Kim M., Chem. Speciation Bioavailability, 22, (2010)

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