Complexes of Nickel(II) with [(Prop-2-en(yn)-1-yl)oxy]ethanimidothioate and Their Applications

被引:0
|
作者
Zalov, A. Z. [1 ]
Kuliev, K. A. [1 ]
Talybov, G. M. [2 ]
Abasguliyeva, U. B. [1 ]
Novruzova, N. A. [1 ]
机构
[1] Azerbaijan State Pedag Univ, AZ-1000 Baku, Azerbaijan
[2] Azerbaijan Tech Univ, AZ-1073 Baku, Azerbaijan
关键词
nickel; ligand; chloroform; nickel complexes; EXTRACTION-SPECTROPHOTOMETRIC DETERMINATION; SIMULTANEOUS PRECONCENTRATION; COBALT; SAMPLES; WATER;
D O I
10.1134/S1070363225600833
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
AbstractThe reactions of nickel(II) with (S)-[(prop-2-en-1-yl)oxy]ethanimidothioate (PENT) and (S)-[(prop-2-yn-1-yl)oxy]ethanimidothioate (PINT) was studied by the extraction-photometric method. The ligands were characterized with IR and NMR spectroscopy. The influence of aqueous phase pH on the formation of Ni(II)L2 complexes and thermal decomposition were studied. The developed extraction-photometric method was applied to determine nickel in wastewater and plant samples.
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页码:764 / 772
页数:9
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