Viscosity, NMR Diffusometry and Light Scattering Data for Aqueous and Aqueous-Salt Solutions of Poly(1-butyl-3-vinylimidazolium bromide)

被引：0

作者：

Korchak, Petr A. ^{[1
]}

Yarchenko, Polina S. ^{[1
]}

Safonova, Evgenia A. ^{[1
]}

Koneva, Alina S. ^{[1
]}

Victorov, Alexey I. ^{[1
]}

机构：

[1] St Petersburg State Univ, St Petersburg 199034, Russia

来源：

CHINESE JOURNAL OF POLYMER SCIENCE | 2025年 / 43卷 / 02期

基金：

俄罗斯科学基金会;

关键词：

Polymerized ionic liquid; Polyelectrolyte solutions; Viscosity; Light scattering; NMR diffusometry; POLYMERIZED IONIC LIQUIDS; POLY(IONIC LIQUID)S; CHARGE-DENSITY; AMINO-ACID; POLYELECTROLYTE; VISCOELASTICITY; CONDUCTIVITY; EXTRACTION; DYNAMICS;

D O I：

10.1007/s10118-025-3269-y

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(1-butyl-3-vinylimidazolium bromide) is a polymerized ionic liquid (PILs), a relatively new class of materials that combines the attractive properties of ionic liquids (ILs) and polyelectrolytes and finds wide applications. The backbone of this PIL is composed of quaternary imidazolium salts, which are among the most promising and popular ILs. However, little is known about the physicochemical characteristics of the aqueous solutions of this PIL. In this study, we synthesized and characterized samples of this PIL and obtained experimental data on the viscosity, static and dynamic light scattering, and nuclear magnetic resonance diffusometry for aqueous and aqueous KBr solutions with varying polymer contents at T=298.15 K. We discuss the effects of the polymer concentration and salinity on the behavior of the solution.

引用

页码：380 / 391

页数：12

共 9 条

[1] Aggregates of Isotactic Poly(methacrylic acid) Chains in Aqueous CsC1 Solutions: a Static and Dynamic Light Scattering Study
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ACTA CHIMICA SLOVENICA, 2015, 62 (03) : 546 - 554
[2] Volumetric properties of 1-butyl-3-methylimidazolium bromide in aqueous solutions of D(-)-ribose and D(-)-arabinose at different temperatures
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Banipal, Parampaul K.
Banipal, Tarlok S.
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[3] Conductometric and spectroscopic studies of cetyltrimethylammonium bromide in aqueous solutions of imidazolium based ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate
Kumar, Harsh
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JOURNAL OF MOLECULAR LIQUIDS, 2015, 211 : 1018 - 1025
[4] Effect of temperature on the viscosity of dilute aqueous solutions of 1-butyl-3-methyl imidazolium chloride [Bmim+][Cl-]
Efecto de la temperatura sobre la viscosidad de soluciones acuosas diluidas de Cloruro de 1-butil-3-metil Imidazolio
Páez, M.S. (mspaezm@unal.edu.co), 1600, Centro de Informacion Tecnologica (25): : 185 - 190
[5] Partitioning of Amino Acids in the Aqueous Biphasic System Containing the Water-Miscible Ionic Liquid 1-Butyl-3-Methylimidazolium Bromide and the Water-Structuring Salt Potassium Citrate
Zafarani-Moattar, Mohammed Taghi
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BIOTECHNOLOGY PROGRESS, 2011, 27 (04) : 986 - 997
[6] Small-angle neutron scattering studies of model protein denaturation in aqueous solutions of the ionic liquid 1-butyl-3-methylimidazolium chloride
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Heller, William T.
Chemical Engineering Journal, 2009, 147 (01): : 6 - 12
[7] Ionic liquid 1-butyl-3-methylimidazolium bromide as a promoter for the formation and extraction capability of poly(ethylene glycol)-potassium citrate aqueous biphasic system at T=298.15 K
Hamzehzadeh, Sholeh
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FLUID PHASE EQUILIBRIA, 2014, 382 : 80 - 88
[8] The study of vapor-liquid equilibria of 1-ethyl-3-methyl imidazolium chloride and 1-butyl-3-methyl imidazolium chloride in lithium bromide aqueous solutions and their corresponding binary systems at 298.15 K.
Zafarani-Moattar, Mohammed Taghi
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CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 2013, 40 : 16 - 23
[9] The study of volumetric, acoustic and transport properties of ionic liquid, 1-butyl-3-methyl imidazolium chloride [Bmim][Cl] in aqueous lithium bromide solutions at T=298.15-318.15 K
Zafarani-Moattar, Mohamad Taghi
Frouzesh, Farshid
Rafiee, Hamid Reza
FLUID PHASE EQUILIBRIA, 2014, 376 : 40 - 47

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