A novel pillar-layered MOF with urea linkers as a capable catalyst for synthesis of new 1,8-naphthyridines via the anomeric-based oxidation

被引:1
作者
Beiranvand, Masoumeh [1 ]
Habibi, Davood [1 ]
Khodakarami, Hosein [1 ]
机构
[1] Bu Ali Sina Univ, Fac Chem & Petr Sci, Dept Organ Chem, Hamadan, Iran
关键词
Metal-organic framework; Heterogeneous; 1,8-Naphthyridines; Tandem; Anomeric; METAL-ORGANIC FRAMEWORKS; DERIVATIVES; EFFICIENT;
D O I
10.1038/s41598-024-66539-3
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Metal-based catalysts play an essential role in organic chemistry and the chemical industry. This research designed and successfully synthesized a pillar-layered metal-organic framework (MOF) with the urea linkers, namely Basu-HDI, as a novel and efficient heterogeneous catalyst. Various techniques such as FT-IR, EDX, elemental mapping, SEM, XRD, BET, and TGA/DTA studied its structure and morphology. Then, we investigated the synthesis of new 1,8-naphthyridines utilizing Basu-HDI in mild conditions via a one-pot, three-component tandem Knoevenagel/Michael/ cyclization/anomeric-based oxidation reaction. Final products were achieved by anomeric-based oxidation without employing an oxidation agent. Remarkably, this tandem process gave a good range of new 1,8-naphthyridines with high yields in a short reaction time. The pure products were confirmed by FT-IR, 1H NMR, 13C NMR, and mass spectrometry techniques. Moreover, the introduced catalyst showed good efficiency and stability and can be reused four times without significantly reducing efficiency.
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页数:15
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