Green and sustainable hydrogen production from methane and methane water mixture using aluminosilicate catalyst and gamma radiations

被引:0
作者
Ali, Imran [1 ]
Imanova, Gunel [2 ,3 ,4 ,5 ]
Agayev, Teymur [2 ]
Aliyev, Anar [2 ]
Kurniawan, Tonni Agustiono [6 ]
Jumah, Abdulrahman Bin [7 ]
机构
[1] Jamia Millia Islamia, Dept Chem, New Delhi 110025, India
[2] Minist Sci & Educ Republ Azerbaijan, Inst Radiat Problems, 9 BVahabzade Str, Baku AZ1143, Azerbaijan
[3] Khazar Univ, Dept Phys & Elect, 41 Mahsati Str, Baku AZ1096, Azerbaijan
[4] Western Caspian Univ, Baku AZ-1001, Azerbaijan
[5] Azerbaijan State Univ Econ UNEC, UNEC Res Ctr Sustainable Dev & Creen Econ, 6 Istiglaliyyat Str, Baku 1001, Azerbaijan
[6] Xiamen Univ, Coll Environm & Ecol, Xiamen 361102, Fujian, Peoples R China
[7] King Saud Univ, Coll Engn, Dept Chem Engn, POB 800, Riyadh 11421, Saudi Arabia
关键词
Hydrogen production; Methane steam mixture; Radiation-thermal processes; Mechanism; Kinetics; DECOMPOSITION; TEMPERATURE;
D O I
10.1007/s10967-024-09899-4
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Hydrogen production was achieved by irradiating methane and methane-water mixtures at 300-873 K on aluminosilicate (Al-O-Si) surface with gamma radiations. Results with methane molecules were two times higher at 773 K i.e. an increase in G(H2) yields from 1.2 to 2.3 molecules/100 eV. The efficiency of energy transfer in Al-O-Si-methane system was less than in Al-O-Si-water system. The maximum amount of hydrogen produced was 65.0 x 1017 molecules/g at 10 atm methane pressure, 773 K temperature, 8 h and 1.2 Gy/s radiation dose. The amount of hydrogen produced is quite good and the results may be used on a pilot scale.
引用
收藏
页码:1533 / 1540
页数:8
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