Corn husk biowaste-derived porous carbon as efficient electrode material for supercapacitor

被引:2
作者
Macherla, Nagaraju [1 ]
Nerella, Manjula [2 ]
Ramana, C. V. [3 ,4 ]
Kumari, Kusum [2 ]
Koutavarapu, Ravindranadh [5 ]
Shim, Jaesool [1 ]
机构
[1] Yeungnam Univ, Sch Mech Engn, Gyongsan 38541, South Korea
[2] Natl Inst Technol, Dept Phys, Warangal 506004, Telangana, India
[3] Univ Texas El Paso, Ctr Adv Mat Res CMR, El Paso, TX 79968 USA
[4] Univ Texas El Paso, Dept Aerosp & Mech Engn, El Paso, TX 79968 USA
[5] GMR Inst Technol, Dept Basic Sci & Humanities, Phys Div, Rajam 532127, India
基金
新加坡国家研究基金会;
关键词
Supercapacitor; Porous carbon; Biowaste; Electrode material; Chemical activation; Energy storage; CHEMICAL ACTIVATION; SURFACE-AREA; NITROGEN; CONVERSION; COMPOSITE; INSIGHTS; STORAGE;
D O I
10.1007/s11581-024-06028-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Transforming biowaste into value-added porous carbon is highly significant in scientific and industrial point of view. The present research exploits corn husk biowaste as a source for producing high-quality interconnecting ordered porous carbons. Corn husk porous carbon (CHPC) is produced by employing a two-step carbonization and chemical activation process. Using structural and morphological characterisation tools, the effect of activation temperature on the characteristics of the resultant porous carbon is carefully examined. CHPC activated at 800 degrees c (CHPC-800) shows prominent feature like high specific surface area (similar to 1583 m(2) g(-1)) and interconnected ordered porous morphology (meso- and microporosity). Electrochemical investigations revealed that CHPC-800 could be able to deliver a maximum specific capacitance of 133 F g(-1) at a current density of 1 A g(-1) in symmetrical supercapacitor. Further, CHPC-800 also showed impressive electrochemical cycling stability (93.5% after 4500 cycles). CHPC-800 is benefited from both surge in surface area and ordered porosity resulting in better electrochemical properties. The findings suggest that porous carbon, which can be easily synthesised from abundantly available corn husk biowaste, could be a viable alternative for energy storage.
引用
收藏
页码:2085 / 2097
页数:13
相关论文
共 60 条
[41]   Insights into the thermochemical evolution of maleic anhydride-initiated esterified starch to construct hard carbon microspheres for Lithium-ion batteries [J].
Song, Ming-Xin ;
Xie, Li-Jing ;
Cheng, Jia-Yao ;
Yi, Zong-Lin ;
Song, Ge ;
Jia, Xiao-Yang ;
Chen, Jing-Peng ;
Guo, Quan-Gui ;
Chen, Cheng-Meng .
JOURNAL OF ENERGY CHEMISTRY, 2022, 66 :448-458
[42]   Facile self-templating large scale preparation of biomass-derived 3D hierarchical porous carbon for advanced supercapacitors [J].
Song, Shijiao ;
Ma, Fangwei ;
Wu, Guang ;
Ma, Di ;
Geng, Weidan ;
Wan, Jiafeng .
JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (35) :18154-18162
[43]   Biomass-Derived Activated Porous Carbon from Rice Straw for a High-Energy Symmetric Supercapacitor in Aqueous and Non-aqueous Electrolytes [J].
Sudhan, N. ;
Subramani, K. ;
Karnan, M. ;
Ilayaraja, N. ;
Sathish, M. .
ENERGY & FUELS, 2017, 31 (01) :977-985
[44]   From coconut shell to porous graphene-like nanosheets for high-power supercapacitors [J].
Sun, Li ;
Tian, Chungui ;
Li, Meitong ;
Meng, Xiangying ;
Wang, Lei ;
Wang, Ruihong ;
Yin, Jie ;
Fu, Honggang .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (21) :6462-6470
[45]   Novel interconnected hierarchical porous carbon electrodes derived from bio-waste of corn husk for supercapacitor applications [J].
Surya, K. ;
Michael, M. S. .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2020, 878
[46]   Synthesis of layered 2H-MoSe2 nanosheets for the high-performance supercapacitor electrode material [J].
Upadhyay, Sanjay ;
Pandey, O. P. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2021, 857
[47]   Biomass-derived porous activated carbon nanofibers from Sapindus trifoliatus nut shells for high-performance symmetric supercapacitor applications [J].
Vinayagam, Murugan ;
Suresh Babu, Rajendran ;
Sivasamy, Arumugam ;
de Barros, Ana Lucia Ferreira .
CARBON LETTERS, 2021, 31 (06) :1133-1143
[48]   Biomass derived carbon for energy storage devices [J].
Wang, Jie ;
Nie, Ping ;
Ding, Bing ;
Dong, Shengyang ;
Hao, Xiaodong ;
Dou, Hui ;
Zhang, Xiaogang .
JOURNAL OF MATERIALS CHEMISTRY A, 2017, 5 (06) :2411-2428
[49]   Pseudocapacitive contributions to electrochemical energy storage in TiO2 (anatase) nanoparticles [J].
Wang, John ;
Polleux, Julien ;
Lim, James ;
Dunn, Bruce .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (40) :14925-14931
[50]   Performance study of high energy storage supercapacitor from waste corn husk biomass electrode materials [J].
Xiang, Jing ;
Zheng, Hong ;
Xue, Hao ;
Huang, Wenjing ;
Yuan, Peng ;
Yang, Taotao ;
Yang, Lingxin ;
Wang, Qin ;
Zhang, Yurun .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2024, 194