Electrochemical performance improvement of coin cell lithium-ion lithium manganese dioxide battery

被引：0
作者：
Shiue, Angus [1 ]
Chin, Kai-Yen [1 ]
Chen, Po-Chou [1 ]
Lin, Jia-Xian [1 ]
Lin, Cheng-Liang [1 ]
Chang, Shu-Mei [1 ]
Leggett, Graham [2 ]
机构：
[1] Natl Taipei Univ Technol, Dept Mol Sci & Engn, Sec 3,Chung Hsiao E Rd, Taipei 10608, Taiwan
[2] St Johns Innovat Ctr, LI COR Biosci, Cambridge CB4 0WS, England
来源：
INTERNATIONAL JOURNAL OF LOW-CARBON TECHNOLOGIES | 2025年 / 20卷
关键词：
manganese oxide; lithium-ion battery; nonwoven; electrolyte additives; calcination; MNO2; MEMBRANE; SEPARATORS; MECHANISM; ELECTRODE; ALPHA-MNO2; CHALLENGES; OXYGEN; BETA; LIFE;
D O I：
10.1093/ijlct/ctaf002
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Lithium-manganese oxide batteries are known for their long-term storage capabilities, characterized by low impedance and high discharge capacity. This study aims to enhance these properties by optimizing key battery components. XRD analysis of MnO2 (MD) powder, heat-treated at 400 degrees C for 5 hours, revealed improved discharge capacity. In addition, hot-pressed polypropylene nonwoven separators with electrolyte absorption exceeding 67 mg successfully reduced after-discharge impedance with minimal capacity loss (0.96%-1.26%). Last, the use of electrolyte additives led to a significant reduction in impedance for commercial electrolytes X and Y, contributing to overall battery performance improvement.
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收藏
页码：466 / 479
页数：14
相关论文
共 51 条
[31]  
Lensch-Franzen C., 2020, MTZ Worldw, V81, P68, DOI [10.1007/s38313-020-0292-9, DOI 10.1007/S38313-020-0292-9]
[32]   α-MnO2 nanotubes: high surface area and enhanced lithium battery properties [J].
Li, Lihong ;
Nan, Caiyun ;
Lu, Jun ;
Peng, Qing ;
Li, Yadong .
CHEMICAL COMMUNICATIONS, 2012, 48 (55) :6945-6947
[33]   Mechanism and Activity of Photocatalytic Oxygen Evolution on Titania Anatase in Aqueous Surroundings [J].
Li, Ye-Fei ;
Liu, Zhi-Pan ;
Liu, LuLu ;
Gao, Weiguo .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (37) :13008-13015
[34]   Engineering stable electrode-separator interfaces with ultrathin conductive polymer layer for high-energy-density Li-S batteries [J].
Li, Yuanjian ;
Wang, Wenyu ;
Liu, Xiaoxiao ;
Mao, Eryang ;
Wang, Mintao ;
Li, Guocheng ;
Fu, Lin ;
Li, Zhen ;
Eng, Alex Yong Sheng ;
Seh, Zhi Wei ;
Sun, Yongming .
ENERGY STORAGE MATERIALS, 2019, 23 :261-268
[35]   All-Integrated Bifunctional Separator for Li Dendrite Detection via Novel Solution Synthesis of a Thermostable Polyimide Separator [J].
Lin, Dingchang ;
Zhuo, Denys ;
Liu, Yayuan ;
Cui, Yi .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (34) :11044-11050
[36]   Enabling High-Energy, High-Voltage Lithium-Ion Cells: Standardization of Coin-Cell Assembly, Electrochemical Testing, and Evaluation of Full Cells [J].
Long, Brandon R. ;
Rinaldo, Steven G. ;
Gallagher, Kevin G. ;
Dees, Dennis W. ;
Trask, Stephen E. ;
Polzin, Bryant J. ;
Jansen, Andrew N. ;
Abraham, Daniel P. ;
Bloom, Ira ;
Bareno, Javier ;
Croyz, Jason R. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2016, 163 (14) :A2999-A3009
[37]   A Guide to Full Coin Cell Making for Academic Researchers [J].
Murray, Vivian ;
Hall, David S. ;
Dahn, J. R. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2019, 166 (02) :A329-A333
[38]   ELECTROCHEMISTRY OF MANGANESE-DIOXIDE IN LITHIUM NONAQUEOUS CELL .1. X-RAY DIFFRACTIONAL STUDY ON THE REDUCTION OF ELECTROLYTIC MANGANESE-DIOXIDE [J].
OHZUKU, T ;
KITAGAWA, M ;
HIRAI, T .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1989, 136 (11) :3169-3174
[39]   Binder-Free Nanoparticulate Coating of a Polyethylene Separator via a Reactive Atmospheric Pressure Plasma for Lithium-Ion Batteries with Improved Performances [J].
Qin, Sicheng ;
Wang, Ming ;
Wang, Chaoliang ;
Jin, Yichao ;
Yuan, Nana ;
Wu, Zhuangchun ;
Zhang, Jing .
ADVANCED MATERIALS INTERFACES, 2018, 5 (19)
[40]   Performance and cost of materials for lithium-based rechargeable automotive batteries [J].
Schmuch, Richard ;
Wagner, Ralf ;
Horpel, Gerhard ;
Placke, Tobias ;
Winter, Martin .
NATURE ENERGY, 2018, 3 (04) :267-278
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