Electrochemical performance improvement of coin cell lithium-ion lithium manganese dioxide battery

被引:0
作者
Shiue, Angus [1 ]
Chin, Kai-Yen [1 ]
Chen, Po-Chou [1 ]
Lin, Jia-Xian [1 ]
Lin, Cheng-Liang [1 ]
Chang, Shu-Mei [1 ]
Leggett, Graham [2 ]
机构
[1] Natl Taipei Univ Technol, Dept Mol Sci & Engn, Sec 3,Chung Hsiao E Rd, Taipei 10608, Taiwan
[2] St Johns Innovat Ctr, LI COR Biosci, Cambridge CB4 0WS, England
关键词
manganese oxide; lithium-ion battery; nonwoven; electrolyte additives; calcination; MNO2; MEMBRANE; SEPARATORS; MECHANISM; ELECTRODE; ALPHA-MNO2; CHALLENGES; OXYGEN; BETA; LIFE;
D O I
10.1093/ijlct/ctaf002
中图分类号
O414.1 [热力学];
学科分类号
摘要
Lithium-manganese oxide batteries are known for their long-term storage capabilities, characterized by low impedance and high discharge capacity. This study aims to enhance these properties by optimizing key battery components. XRD analysis of MnO2 (MD) powder, heat-treated at 400 degrees C for 5 hours, revealed improved discharge capacity. In addition, hot-pressed polypropylene nonwoven separators with electrolyte absorption exceeding 67 mg successfully reduced after-discharge impedance with minimal capacity loss (0.96%-1.26%). Last, the use of electrolyte additives led to a significant reduction in impedance for commercial electrolytes X and Y, contributing to overall battery performance improvement.
引用
收藏
页码:466 / 479
页数:14
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