Experimental Measurements and Modeling of Density and Viscosity for Methyl Caprate+1-Alkanol at Atmospheric Pressure and Different Temperatures

被引:5
作者
Almasi, Mohammad [1 ]
Hernandez, Ariel [2 ]
机构
[1] Malayer Univ, Fac Sci, Dept Appl Chem, Malayer 65174, Iran
[2] Univ Catolica Santisima Concepcion, Fac Ingn, Dept Ingn Ind, Concepcion 2850, Chile
关键词
Correlations for viscosity; Experimental liquid density; Experimental liquid viscosity; Methyl caprate+1-alkanol mixtures; PC-SAFT; Redlich-Kister equation; PERTURBED-CHAIN SAFT; FATTY-ACID METHYL; EQUATION; ESTERS; STATE;
D O I
10.1007/s10765-024-03444-x
中图分类号
O414.1 [热力学];
学科分类号
摘要
This study provides new experimental data for the density and viscosity of mixtures containing methyl caprate and 1-alkanol (1-propanol to 1-hexanol) at 0.1 MPa and different temperatures (293.15 K to 323.15 K). We analyzed the molecular interactions between the components and found that are weak. The PC-SAFT equation of state accurately modeled the density of the mixtures without fitted parameters. This equation of state considered hydrogen bonding between methyl caprate and 1-alkanol. Moreover, two correlations for viscosity were successfully applied to fit the experimental viscosity data with good accuracy.
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页数:20
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