Synergistic effects in CuO/SnO2/Ti3C2Tx nanohybrids: Unveiling their potential as supercapacitor cathode material

被引:7
|
作者
Ramachandran, Tholkappiyan [1 ,2 ]
Pachamuthu, M. P. [3 ]
Karthikeyan, G. [4 ]
Hamed, Fathalla [5 ]
Rezeq, Moh'd [2 ,6 ]
机构
[1] Khalifa Univ Sci & Technol, Dept Phys, POB 127788, Abu Dhabi, U Arab Emirates
[2] Saveetha Univ, Saveetha Inst Med & Tech Sci, Saveetha Sch Engn, Dept Phys, Chennai 602105, India
[3] Bannari Amman Inst Technol, PIC Sensors Lab, Dept Chem, Erode, India
[4] Irkutsk Natl Res Tech Univ, Baikal Sch BRICS, Dept Chem & Biotechnol, 83, Lermontov St, Irkutsk 664074, Russia
[5] United Arab Emirates Univ, Coll Sci, Dept Phys, POB 15551, Al Ain, U Arab Emirates
[6] Khalifa Univ Sci & Technol, Syst Chip Ctr SoCC, POB 127788, Abu Dhabi, U Arab Emirates
关键词
Energy storage; Supercapacitors; Synergistic effects; Capacitive and diffusion distribution; CuO/SnO2/MXene nanohybrids; HIERARCHICAL ARCHITECTURE; COMPOSITE ELECTRODE; PERFORMANCE; CO; MXENE;
D O I
10.1016/j.mssp.2024.108486
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
In the field of materials science, a synergistic effect occurs when the combined physical and chemical properties of a composite material show significant improvement compared to the properties of its individual components. In this study, we synthesized a novel nanosheet-like structure composed of copper oxide (CuO) and tin oxide (SnO2) dispersed on MXene (Ti3C2Tx) sheets using an ultrasonicated coprecipitation method, and then we explored its synergistic effects. The CuO/SnO2/MXene nanohybrids were characterized through SEM, HRTEM, XRD, XPS, and BET analysis, confirming successful synthesis and evident synergy between MXene and CuO/SnO2. The electrochemical behaviour of the nanohybrid structure was investigated using different electrochemical techniques. CuO/SnO2/MXene revealed a high capacitance of 683.5 Fg(-1) at 1 Ag-1 in a 2 M H2SO4 electrolyte, with 85 % cycling performance after 10,000 cycles. Notably, this performance surpassed that of MXene-Ti3C2Tx and CuO/SnO2 separately, which achieved only 102.8 and 378.2 Fg(-1) capacitance with 60 % and 76 % cycling stability, respectively. These incredible results are attributed to CuO/SnO2/MXene nanohybrids' synergistic effects, whereby enhance the surface area, electrical conductivity, and availability of active sites and enhanced electrochemical performance. This research offers a promising solution for advancing supercapacitor electrode materials through the creation of a novel nanosheet structure that leverages synergistic effects.
引用
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页数:10
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