Synthesis of magnetic chitosan-composite biochar and its removal of copper ions (Cu2+) and methylene blue (MB) dye from aqueous solutions

This study presents the synthesis and evaluation of a magnetic chitosan-modified biochar (M-BC-CS) composite, developed from waste maize straw, for the efficient removal of copper ions (Cu2+) and methylene blue (MB) dye from aqueous solutions. The composite was characterized using advanced techniques such as SEM, BET, FTIR, XPS, and XRD, confirming its enhanced surface area, porosity, and magnetic properties. The study is aimed at investigating the optimal conditions for adsorption of Cu2+ and MB by M-BC-CS through analysis of the influence of diverse adsorbent dosages, pH levels, reaction times, and initial solution concentrations. The findings demonstrated that the equilibrium duration for the adsorption of Cu2+ and MB by M-BC-CS was 60 min, resulting in corresponding equilibrium adsorption quantities of 54.42 mg/g and 67.23 mg/g, respectively. To elucidate the adsorption mechanism, the present investigation applied the pseudo-second-order kinetic model and the Langmuir isotherm. The outcomes suggested that the adsorption process is attributable to single molecular layer chemisorption. XPS and FTIR analysis determined that ion exchange and electrostatic interactions are the predominant mechanisms responsible for the simultaneous adsorption of Cu2+ and MB, and a competitive relationship exists between these mechanisms. In addition, M-BC-CS exhibited exceptional magnetic separation performance, enabling effortless and effective separation when exposed to an external magnetic field. Furthermore, the results demonstrated that M-BC-CS has good reusability and high adsorption capacity also in real wastewater, thus emphasizing its potential as a promising adsorbent for the elimination of Cu2+ and MB from aqueous solutions. Graphical Abstract: (Figure presented.) © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024.