Chemiluminescence Study of the Generation of Active Oxygen Species on the Surface of TiO2:MoO3 Charge-Accumulating Photocatalysts

被引：0
作者：
Sviridova, T. V. [1 ]
Sadovskaya, L. Yu [1 ]
Sviridov, D. V. [1 ]
机构：
[1] Belarusian State Univ, Minsk, BELARUS
来源：
JOURNAL OF APPLIED SPECTROSCOPY | 2024年 / 91卷 / 05期
关键词：
chemiluminescence; hydrogen peroxide; photocatalysis; titanium dioxide; molybdenum trioxide; Fenton reaction;
D O I：
10.1007/s10812-024-01810-z
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
A chemiluminescence technique was used to establish that, in contrast to TiO2 photocatalysts, TiO2:MoO3 composite photocatalysts suppress the photogeneration of superoxide ions, while the capture of photoelectrons in the MoO3 phase to give reduced Mo(V) states creates conditions for the long-term generation of hydrogen peroxide capable of acting as a biocide. The TiO2:MoO3 accumulating photocatalysts were shown to be fully reusable and the cycle of photocharging followed hydrogen peroxide generation can be repeated multiple times.
引用
收藏
页码：984 / 988
页数：5
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