Near-Infrared Light-Driven H2O2 Generation via Metalloporphyrin-Based Covalent Organic Frameworks and Nanodisks

被引：5

作者：

Yoshikawa, Aya ^{[1
]}

Shigemitsu, Hajime ^{[1
,3
,4
,5
]}

Li, Xinxi ^{[2
]}

Fujitsuka, Mamoru ^{[2
]}

Osakada, Yasuko ^{[2
,6
]}

Kida, Toshiyuki ^{[1
,3
]}

机构：

[1] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

[2] Osaka Univ, SANKEN Inst Sci & Ind Res, Osaka, Ibaraki 5670047, Japan

[3] Osaka Univ, Ctr Future Innovat CFi, Grad Sch Engn, Suita, Osaka 5650871, Japan

[4] Osaka Univ, Inst Open & Transdisciplinary Res Initiat OTRI, Integrated Frontier Res Med Sci Div, Suita, Osaka 5650871, Japan

[5] Osaka Univ, Global Ctr Med Engn & Informat, Suita, Osaka 5650871, Japan

[6] Osaka Univ, Inst Adv Cocreat Studies, Suita, Osaka 5650871, Japan

来源：

ACS APPLIED ENERGY MATERIALS | 2024年 / 7卷 / 20期

关键词：

near-infrared light; hydrogen peroxide; covalentorganic framework; porphyrin; photocatalysis;

D O I：

10.1021/acsaem.4c02171

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hydrogen peroxide (H2O2) is a crucial chemical with widespread applications in our daily lives and as an energy material. Recently, the generation of H2O2 using light energy has garnered significant attention for its potential contribution to a sustainable society. In particular, near-infrared region (NIR) light-driven H2O2 generation holds great promise for solar energy utilization. However, due to the low energy of NIR light, developing an NIR-driven photocatalyst remains a challenge. In this study, we demonstrate that nickel-coordinated porphyrin-based covalent organic frameworks (COFs) can efficiently generate H2O2 under NIR light irradiation (700-800 nm). Additionally, the efficiency was improved (7.0-hold) by covalent organic nanodisks (CONs) exfoliated from the COFs stacking structure. Furthermore, the CONs were able to generate H2O2 under 1000 nm NIR light irradiation.

引用

页码：9084 / 9088

页数：5

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