Effect of mesh aluminum alloy on hydrogen and propane explosion characteristics

被引:0
|
作者
Hu, Shoutao [1 ]
Zhang, Zhiwei [1 ]
Gong, Hao [1 ]
Wang, Wan [2 ]
Nie, Baisheng [3 ]
Hong, Zijin [4 ]
Li, Ruxia [1 ]
机构
[1] Beijing Inst Petrochem Technol, Sch Safety Engn, Beijing, Peoples R China
[2] China Natl Inst Standardizat, Beijing, Peoples R China
[3] Chongqing Univ, Sch Resources & Safety Engn, Chongqing 400044, Peoples R China
[4] Beijing Shuguang Aviat Elect Co Ltd, Beijing, Peoples R China
关键词
Combustible gas; Mesh aluminum alloy; Numerical simulation; Chain reaction; Free radical; COMBUSTION; SCHEMES;
D O I
10.1016/j.psep.2024.10.064
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In order to explore the effect of mesh aluminum alloy (MAA) on the explosion characteristics of different types of gases, experiments were conducted by filling MAA in hydrogen and propane explosion pipes. The explosion characteristic parameters of hydrogen and propane with different volume fractions under the action of MAA were obtained. The chain reaction process and thermodynamic reaction mechanism of hydrogen and propane explosions were studied using the numerical simulation software CHEMKIN-PRO and Materials Studio. The experimental results show that MAA significantly promotes hydrogen explosions but inhibits propane explosions. Simulation results show that center dot H, center dot O, and center dot OH are key radicals in the hydrogen explosion process. As the hydrogen volume fraction increases, the number of radicals in the reaction system also increases. When MAA is filled in the hydrogen explosion test pipe, the turbulence of the flame structure inside the pipe increases the collision probability between key radicals such as center dot H, center dot O, and center dot OH, sharply increasing the temperature of the explosion reaction system, resulting in a promoting effect of MAA on hydrogen explosions. When MAA is introduced into the propane explosion test pipe, it creates a barrier and wall effect. This reduces the number of key radicals in the reaction system and lowers the likelihood of radical collisions, which slows down the rates of multiple chain reactions and inhibits the propane explosion. Thermodynamically, it can be seen that propane requires more energy than hydrogen for key elementary reactions to explode, making it more difficult to react.
引用
收藏
页码:946 / 959
页数:14
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