Cyaphide group transfer from covalent metal complexes: contrasting pathways to transmetallation

被引：0
作者：
Yang, Eric S. [1 ]
Goicoechea, Jose M. [2 ]
机构：
[1] Univ Oxford, Dept Chem, Chem Res Lab, 12 Mansfield Rd, Oxford OX1 3TA, England
[2] Indiana Univ, Dept Chem, 800 East Kirkwood Ave, Bloomington, IN 47405 USA
来源：
CHEMICAL COMMUNICATIONS | 2025年 / 61卷 / 04期
基金：
英国工程与自然科学研究理事会;
关键词：
CP; LIGAND; BOND;
D O I：
10.1039/d4cc06131d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We describe two contrasting transmetallation reactions between the gold(i) cyaphide complex, Au(IDipp)(CP) (IDipp = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene), and low oxidation state main-group and transition-metal complexes. The reactivity observed highlights the pseudo-halide character of the cyaphide ion.
引用
收藏
页码：725 / 727
页数：3
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