Boosting supercapacitor performance with high-specific surface area porous carbon derived from sugarcane bagasse

被引:0
|
作者
Kang, Zhongnan [1 ]
Xu, Dekun [1 ]
Zhao, Lele [1 ]
Liu, Dong [1 ,2 ]
机构
[1] Wuhan Inst Technol, Sch Chem & Environm Engn, Hubei Key Lab Novel Reactor & Green Chem Technol, Wuhan 430205, Peoples R China
[2] Wuhan Inst Technol, Key Lab Green Chem Proc, Minist Educ, Engn Res Ctr Phosphorus Resources Dev & Utilizat, Wuhan 430205, Peoples R China
关键词
Sugarcane bagasse; Wet method; Specific surface area; Supercapacitor; ACTIVATED CARBON;
D O I
10.1016/j.est.2024.114718
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Porous carbon materials with an ultra-large specific surface area were synthesized from sugarcane bagasse using a wet mixing process. Initially, the waste sugarcane bagasse underwent pre-carbonization at 550 degrees C, resulting in a carbonized material (PC). This PC was then mixed with the activator KOH and subjected to high-temperature activation to produce the porous carbon material. The morphology and structure of the porous carbon were effectively modified by varying the mass ratio of PC to KOH and the mixing method (dry or wet). The electrochemical performance of the synthesized materials was analyzed, revealing that the material produced with a 1:3 mass ratio of PC to KOH using the wet mixing method (WBC-3) exhibited a well-developed pore structure and a specific surface area of 3549.6 m2/g. When employed as an electrode material, WBC-3 demonstrated exceptional performance, achieving a specific capacitance of 370 F/g at a current density of 0.5 A/g. The assembled device attained energy densities of 8.3 Wh/kg in 6 M KOH and 16.4 Wh/kg in 1 M Na2SO4, respectively. Moreover, it exhibited remarkable cyclic stability, retaining 95.3 % of its initial specific capacitance after 8000 chargedischarge cycles at a current density of 10 A/g.
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页数:10
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