Facile and efficient stereospecific deamination of aziridines using task-specific silica immobilized organosilane-based nitrite ionic liquid

被引：0
|
作者：
Valizadeh, Hassan [1 ]
Vessally, Esmail [2 ,3 ]
机构：
[1] Azarbaijan Shahid Madani Univ, Fac Sci, Dept Chem, Tabriz, Iran
[2] Payame Noor Univ, Dept Chem, Tehran, Iran
[3] Univ Econ UNEC, Composite Mat Sci Res Ctr Azarbaijan State, 194 M Mukhtarov str, Baku, Azerbaijan
来源：
MONATSHEFTE FUR CHEMIE | 2024年 / 155卷 / 11期
关键词：
Aziridine; Deamination; Nitrite-ionic liquid; Solvent-free; SOLVENT-FREE; CATALYST-FREE; DERIVATIVES;
D O I：
10.1007/s00706-024-03254-9
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Various cis- and trans-aziridine derivatives were deaminated via the reaction with task-specific silica immobilized organosilane-based nitrite ionic liquid. Corresponding cis- or trans-alkenes were produced as stereospecific products in good-to-excellent yields. The advantages of this method include the one-pot procedure, operational simplicity, solvent-free, and very short reaction times. Simple handling of this nitrite anion source nanoparticles and thus lowering the risks and hazards of a chemical process can offer other important advantages.
引用
收藏
页码：1125 / 1129
页数：5
相关论文
共 50 条
  • [1] Facile Synthesis of Benzotriazole Derivatives Using Nanoparticles of Organosilane-Based Nitrite Ionic Liquid Immobilized on Silica and Two Room-Temperature Nitrite Ionic Liquids
    Valizadeh, Hassan
    Gholipour, Hamid
    Mahmoodian, Manzar
    SYNTHETIC COMMUNICATIONS, 2013, 43 (20) : 2801 - 2808
  • [2] Nanoparticles of organosilane-based nitrite ionic liquid immobilized on silica for the diazotization of aniline derivatives and subsequent synthesis of azo dyes
    Valizadeh, Hassan
    Amiri, Mohammad
    Hosseinzadeh, Fatemeh
    DYES AND PIGMENTS, 2012, 92 (03) : 1308 - 1313
  • [3] New nitrite ionic liquid (IL-ONO) and nanoparticles of organosilane-based nitrite ionic liquid immobilized on silica as nitrosonium sources for electrophilic aromatic nitrosation
    Valizadeh, Hassan
    Amiri, Mohammad
    Shomali, Ashkan
    COMPTES RENDUS CHIMIE, 2011, 14 (12) : 1103 - 1108
  • [4] Facile and Stereospecific Synthesis of Various Dienones Using Task-specific Ionic Liquid/Borohydride as Stable and Promoted Hydrogen Release Reagent
    Mouradzadegun, Arash
    Ganjali, Mohammad Reza
    Sabbagh, Elham
    Abadast, Fatemeh
    JOURNAL OF HETEROCYCLIC CHEMISTRY, 2017, 54 (06) : 3574 - 3577
  • [5] An efficient conjugate hydrothiocyanation of chalcones with a task-specific ionic liquid
    Yadav, Lal Dhar S.
    Patel, Rajesh
    Rai, Vijai K.
    Srivastava, Vishnu P.
    TETRAHEDRON LETTERS, 2007, 48 (44) : 7793 - 7795
  • [6] Metal chelate formation using a task-specific ionic liquid
    Harjani, Jitendra R.
    Friscic, Tomislav
    MacGillivray, Leonard R.
    Singer, Robert D.
    INORGANIC CHEMISTRY, 2006, 45 (25) : 10025 - 10027
  • [7] A task-specific ionic liquid based on hydroxypyridinone for lanthanide separation
    Do-Thanh, Chi-Linh
    Luo, Huimin
    Gaugler, James A.
    Dai, Sheng
    SEPARATION AND PURIFICATION TECHNOLOGY, 2022, 301
  • [8] Task-specific basic ionic liquid immobilized on mesoporous silicas: Efficient and reusable catalysts for Knoevenagel condensation in aqueous media
    Zhao, Haihong
    Yu, Ningya
    Ding, Yan
    Tan, Rong
    Liu, Cheng
    Yin, Donghong
    Qiu, Huayu
    Yin, Dulin
    MICROPOROUS AND MESOPOROUS MATERIALS, 2010, 136 (1-3) : 10 - 17
  • [9] A practical and efficient synthesis of quinoxaline derivatives catalyzed by task-specific ionic liquid
    Fang Dong
    Gong Kai
    Fei Zhenghao
    Zhou Xinli
    Liu Zuliang
    CATALYSIS COMMUNICATIONS, 2008, 9 (02) : 317 - 320
  • [10] Liquid-phase synthesis of polyhydroquinoline using task-specific ionic liquid technology
    Legeay, Jean Christophe
    Goujon, Jean Yves
    Eynde, Jean Jacques Vanden
    Toupet, Loic
    Bazureau, Jean Pierre
    JOURNAL OF COMBINATORIAL CHEMISTRY, 2006, 8 (06): : 829 - 833
12345