Deep eutectic solvent-mediated hydrothermal treatment for biomass conversion: a review

被引：11

作者：

Zhu, Hansong ^{[1
]}

He, Xiaotong ^{[2
,3
]}

Xu, Zhixiang ^{[1
]}

Dai, Lichun ^{[2
,3
]}

机构：

[1] Jiangsu Univ, Sch Energy & Power Engn, Zhenjiang 212013, Peoples R China

[2] Minist Agr & Rural Affairs, Biogas Inst, Key Lab Dev & Applicat Rural Renewable Energy, Chengdu 610041, Peoples R China

[3] Chinese Acad Agr Sci, Res Ctr Rural Energy & Ecol, Chengdu 610041, Peoples R China

来源：

GREEN CHEMISTRY | 2025年 / 27卷 / 05期

关键词：

ENZYMATIC-HYDROLYSIS; SEWAGE-SLUDGE; CARBON DOTS; LIGNIN; PRETREATMENT; PHOSPHORUS; EXTRACTION; NANOFIBERS; RECOVERY; NITROGEN;

D O I：

10.1039/d4gc05662k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrothermal treatment is an emerging technology for the processing of biomass into various value-added products. Deep eutectic solvents (DESs) emerge as green solvents for biomass processing. Recently, DES-mediated hydrothermal treatment (DES-HTT) has emerged as a cutting-edge technique for promoting biomass conversion, merging the principles of HTT with the unique properties of DESs. To keep up the pace of rapid development of DESs and HTT, it is necessary to summarize the progress of this green technology. Herein this review summarizes the progress of the use of DES-HTT in biomass conversion, including DES-mediated hydrothermal pretreatment for dewatering, bioconversion and/or fractionation of biomass, DES-mediated hydrothermal extraction of lipid from biomass, and DES-mediated hydrothermal carbonization for functional hydrochar and carbon dot synthesis. This review also analyzes the future challenges and research directions in biomass conversion via DES-HTT. Finally, this review facilitates the valorization of biomass via the combination of advantages from DESs and HTT.

引用

页码：1278 / 1299

页数：22

共 149 条

[1] Deep eutectic solvents formed between choline chloride and carboxylic acids: Versatile alternatives to ionic liquids [J].

Abbott, AP ;

Boothby, D ;

Capper, G ;

Davies, DL ;

Rasheed, RK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (29) :9142-9147

[2]

alhan S. D., 2018, J. Mater. Sci, V53, P15362

[3] Hydrothermal liquefaction of de-oiled Jatropha curcas cake using Deep Eutectic Solvents (DESs) as catalysts and co-solvents [J].

Alhassan, Yahaya ;

Kumar, Naveen ;

Bugaje, Idris M. .

BIORESOURCE TECHNOLOGY, 2016, 199 :375-381

[4] Efficient removal of both basic and non-basic nitrogen compounds from fuels by deep eutectic solvents [J].

Ali, Mohammad Chand ;

Yang, Qiwei ;

Fine, Andrew Aaron ;

Jin, Wenbin ;

Zhang, Zhiguo ;

Xing, Huabin ;

Ren, Qilong .

GREEN CHEMISTRY, 2016, 18 (01) :157-164

[5] Direct conversion of lignocellulosic biomass to biomimetic tendril-like functional carbon helices: a protein friendly host for cytochrome C [J].

Aruchamy, Kanakaraj ;

Bisht, Meena ;

Venkatesu, P. ;

Kalpana, D. ;

Nidhi, M. R. ;

Singh, Nripat ;

Ghosh, Debasis ;

Mondal, Dibyendu ;

Nataraj, Sanna Kotrappanavar .

GREEN CHEMISTRY, 2018, 20 (16) :3711-3716

[6] Tunable fluorescent carbon dots from biowaste as fluorescence ink and imaging human normal and cancer cells [J].

Atchudan, Raji ;

Kishore, Somasundaram Chandra ;

Gangadaran, Prakash ;

Edison, Thomas Nesakumar Jebakumar Immanuel ;

Perumal, Suguna ;

Rajendran, Ramya Lakshmi ;

Alagan, Muthulakshmi ;

Al-Rashed, Sarah ;

Ahn, Byeong-Cheol ;

Lee, Yong Rok .

ENVIRONMENTAL RESEARCH, 2022, 204

[7] Sustainable synthesis of carbon quantum dots from banana peel waste using hydrothermal process for in vivo bioimaging [J].

Atchudan, Raji ;

Edison, Thomas Nesakumar Jebakumar Immanuel ;

Shanmugam, Mani ;

Perumal, Suguna ;

Somanathan, Thirunavukkarasu ;

Lee, Yong Rok .

PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES, 2021, 126

[8] Luminescent Carbon Nanodots: Emergent Nanolights [J].

Baker, Sheila N. ;

Baker, Gary A. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (38) :6726-6744

[9] Techno-economic analysis and life cycle assessment of a biorefinery utilizing reductive catalytic fractionation [J].

Bartling, Andrew W. ;

Stone, Michael L. ;

Hanes, Rebecca J. ;

Bhatt, Arpit ;

Zhang, Yimin ;

Biddy, Mary J. ;

Davis, Ryan ;

Kruger, Jacob S. ;

Thornburg, Nicholas E. ;

Luterbacher, Jeremy S. ;

Rinaldi, Roberto ;

Samec, Joseph S. M. ;

Sels, Bert F. ;

Roman-Leshkov, Yuriy ;

Beckham, Gregg T. .

ENERGY & ENVIRONMENTAL SCIENCE, 2021, 14 (08) :4147-4168

[10] Integrated hydrothermal and deep eutectic solvent-mediated fractionation of lignocellulosic biocomponents for enhanced accessibility and efficient conversion in anaerobic digestion [J].

Basak, Bikram ;

Patil, Swapnil ;

Kumar, Ramesh ;

Ha, Geon-Soo ;

Park, Young-Kwon ;

Khan, Moonis Ali ;

Yadav, Krishna Kumar ;

Fallatah, Ahmed M. ;

Jeon, Byong-Hun .

BIORESOURCE TECHNOLOGY, 2022, 351

← 1 2 3 4 5 6 7 8 9 10 →