Synthesis of multifunctionalized allyl isothiocyanates via isomerization of Morita-Baylis-Hillman adduct-derived allylic thiocyanates

被引：0

作者：

Shin, Sang Gyu ^{[1
]}

Oh, Hyun-Woo ^{[1
]}

Kim, Byung Chang ^{[1
]}

Ok, Jaeseung ^{[1
]}

Lee, Seung In ^{[1
]}

Youn, Sung Pyo ^{[1
]}

Bae, Hyun Hee ^{[1
]}

Park, Ji Yoon ^{[1
]}

Han, Jin Woo ^{[1
]}

Lee, Chang Hoon ^{[1
]}

机构：

[1] Kyungil Univ, Dept Chem Engn, 50 Gamasilgil, Gyongsan 38428, Gyeongbuk, South Korea

来源：

SYNTHETIC COMMUNICATIONS | 2025年 / 55卷 / 03期

关键词：

Allyl isothiocyanate; allylic thiocyanate; Morita-Baylis-Hillman adduct; isomerization; cruciferous vegetables; EFFICIENT SYNTHESIS; INHIBITION; MECHANISM;

D O I：

10.1080/00397911.2024.2441336

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient method to synthesize functionalized allyl isothiocyanates in moderate yields has been demonstrated, based on the isomerization of Morita-Baylis-Hillman adduct-derived allylic thiocyanates. This methodology offers obvious advantages such as easy purification, atom economy, and a broad scope of substrates.

引用

页码：251 / 258

页数：8

共 44 条

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