Metal complexes with selenium-based ligands in organic synthesis

被引：0
作者：
Mamgain, Ritu [1 ]
Kostić, Marina D. [2 ]
Divac, Vera M. [3 ]
Singh, Fateh V. [1 ]
机构：
[1] Chemistry Division, School of Advanced Sciences, Vellore Institute of Technology — Chennai, Vandalur-Kelambakkam Road, Tamil Nadu, Chennai
[2] University of Kragujevac, Institute for Information Technologies, Department of Science, Jovana Cvijića bb, Kragujevac
[3] University of Kragujevac, Faculty of Science, Department of Chemistry, Radoja Domanovića 12, Kragujevac
来源：
Russian Chemical Reviews | 2024年 / 93卷 / 12期
关键词：
catalysis; metal complexes; organoselenium ligands; selenium;
D O I：
10.59761/RCR5143
中图分类号：
学科分类号：
摘要：
Ligand design is a critical element in homogeneous catalysis. Over the past two decades, a variety of selenium-substituted compounds have been used as ligand scaffolds in the development of transition metal catalytic systems. Air and moisture stability, good solubility in various solvents, stability towards oxidation and excellent electron-donating properties of the selenium atom are some of the key features of organoselenium compounds that make them suitable candidates for application as ligands. The metal complexes of selenium ligands are widely known for their ability to catalyze various organic reactions, including but not limited to the Sonogashira coupling reaction, Heck coupling reaction, Suzuki – Miyaura coupling reaction, imidazole arylation, transfer hydrogenation reaction, oxidation of alcohols, and ortho-arylation of phenols. In some cases, exceptionally high catalytic efficiencies have been observed. In addition, catalysis often allows for a wide range of substrate in numerous scenarios, as it is tolerant of different functional groups. This review highlights the main synthetic methods used in the recent development of organoselenium compounds as ligands for the synthesis of transition metal complexes. It also considers their use in various preparative organic transformations. The bibliography includes 133 references. © 2024 Uspekhi Khimii, ZIOC RAS, Russian Academy of Sciences.
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