Effects of Crystalline Diamond Nanoparticles on Silicon Thin Films as an Anode for a Lithium-Ion Battery

被引:1
作者
Tzeng, Yonhua [1 ]
Jhan, Cheng-Ying [1 ]
Sung, Shi-Hong [1 ]
Chiou, Yu-Yang [1 ]
机构
[1] Natl Cheng Kung Univ, Inst Microelect, Tainan 70101, Taiwan
来源
BATTERIES-BASEL | 2024年 / 10卷 / 09期
关键词
lithium-ion battery; thin film; silicon; anode; diamond; electrolyte wetting; ENERGY-STORAGE; CARBONATE FEC; PERFORMANCE; ELECTRODE; DESIGN;
D O I
10.3390/batteries10090321
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Crystalline diamond nanoparticles which are 3.6 nm in size adhering to thin-film silicon results in a hydrophilic silicon surface for uniform wetting by electrolytes and serves as a current spreader for the prevention of a local high-lithium-ion current density. The excellent physical integrity of an anode made of diamond on silicon and the long-life and high-capacity-retention cycling performance are thus achieved for lithium-ion batteries. A specific capacity of 1860 mAh/g(si) was retained after 200 cycles of discharge/charge at an areal current density of 0.2 mA/cm2. This is compared to 1626 mAh/g(si) for a thin-film-silicon anode without the additive of diamond nanoparticles.
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页数:13
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