Suppression of Zinc Dendrites by Bamboo-Inspired Additive for Aqueous Zinc Battery

被引:3
作者
Ye, Tong [1 ,2 ]
Ma, Haiqiang [2 ]
Tang, Shasha [3 ]
Yang, Zhinan [2 ]
Yan, Qinghui [1 ]
Zhang, Liurui [1 ]
He, Haiyong [2 ]
Kuang, Yongbo [2 ]
机构
[1] Ningbo Univ, Sch Mat Sci & Chem Engn, Ningbo 315211, Peoples R China
[2] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Peoples R China
[3] Shandong Inst Nonmet Mat, Jinan 250100, Peoples R China
基金
中国国家自然科学基金;
关键词
bamboo parenchymal cell; dendrite growth; sidereaction; interfacial adsorption; electrolyte additives; aqueous Zn batteries;
D O I
10.1021/acssuschemeng.4c05447
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Rechargeable aqueous zinc-ion batteries (RAZIB) are emerging as promising candidates for renewable energy storage devices, offering superior electrochemical performance, enhanced safety, and economic viability. However, the uncontrolled parasitic reactions and the growth of zinc dendrites resulting from nonuniform deposition impede the practical application of RAZIBs. Herein, inspired by the biological role of bamboo parenchymal cells (BPC), a biomimetic electrolyte additive was introduced to enhance the performance of RAZIBs. Abundant, readily extractable, and environmentally friendly BPC additives integrate the structural characteristics of inorganic materials and the advantages of organic materials. (1) BPC acts as the rich Zn2+ reservoir on the anode by adsorbing Zn2+ from the electrolyte, significantly mitigating concentration polarization. (2) The three-dimensional (3D) polyhedral structure of BPC provides numerous active sites to homogenize Zn2+ flux and inhibit two-dimensional (2D) diffusion on the anode. (3) BPC can suppress hydrogen evolution corrosion and guide Zn deposition toward smoother and denser crystal planes. Consequently, the symmetrical cells containing BPC can stably cycle over 3000 h with minimal voltage hysteresis, and the half-cells exhibit a high average Coulombic efficiency (99.67%) over 380 cycles at 5 mA cm-2. Our strategy demonstrates a zincophilic biomass material for constructing a uniformly zinc-rich and fast-transporting interface layer at the anode interface, paving the way for the sustainable utilization of biomass materials applied in the field of energy storage.
引用
收藏
页码:17468 / 17478
页数:11
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