A refractive sail is a special type of solar sail concept, whose membrane exposed to the Sun's rays is covered with an advanced engineered film made of micro-prisms. Unlike the well-known reflective solar sail, an ideally flat refractive sail is able to generate a nonzero thrust component along the sail's nominal plane even when the Sun's rays strike that plane perpendicularly, that is, when the solar sail attitude is Sun-facing. This particular property of the refractive sail allows heliocentric orbital transfers between orbits with different values of the semilatus rectum while maintaining a Sun-facing attitude throughout the duration of the flight. In this case, the sail control is achieved by rotating the structure around the Sun-spacecraft line, thus reducing the size of the control vector to a single (scalar) parameter. A gradient-index solar sail (GIS) is a special type of refractive sail, in which the membrane film design is optimized though a transformation optics-based method. In this case, the membrane film is designed to achieve a desired refractive index distribution with the aid of a waveguide array to increase the sail efficiency. This paper analyzes the optimal transfer performance of a GIS with a Sun-facing attitude (SFGIS) in a series of typical heliocentric mission scenarios. In addition, this paper studies the attitude control of the Sun-facing GIS using a simplified mathematical model, in order to investigate the effective ability of the solar sail to follow the (optimal) variation law of the rotation angle around the radial direction.