Fracture and fatigue characteristics of monodomain and polydomain liquid crystal elastomers

Liquid crystal elastomers (LCEs), a class of elastomers combining liquid crystals with a polymer network, have garnered significant interest for applications in the field of soft robotics. However, the fracture and fatigue characteristics of LCEs remain poorly understood. This study presents a comprehensive investigation into the fracture and fatigue characteristics of LCEs, focusing on polydomain and monodomain variants subjected to different loading directions. The fracture energy (also called toughness) and fatigue threshold of polydomain and monodomain LCEs were quantitatively measured and compared with selected elastomers. Our experimental results demonstrate that polydomain LCEs exhibit superior fracture energy and fatigue threshold compared to monodomain LCEs. Within the monodomain category, LCEs subjected to parallel loading exhibit larger fracture energy than those under vertical loading, while their fatigue thresholds remain comparable. These findings enhance our understanding of the deformation and failure characteristics of LCEs, which are crucial for their applications in various fields.