A highly sensitive fluorescent probe for the detection of Al3+and study of its practical application

被引:2
作者
Ma, Lei [1 ]
Xia, Baiyang [1 ]
Zhang, Yiying [1 ]
Lv, Jingxue [1 ]
Lv, Yuguang [1 ]
Zhang, Xiangyu [1 ]
机构
[1] Jiamusi Univ, Coll Pharm, Jiamusi 154007, Peoples R China
关键词
Rhodamine 6 G derivatives; Cellular imaging; AL3+detection; SELECTIVE DETECTION; RHODAMINE-B; AQUEOUS-SOLUTION; ON CHEMOSENSOR; SENSOR; FE3+; IONS; CR3+; PB2+; HG2+;
D O I
10.1016/j.molstruc.2024.138886
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel fluorescent probe named NJQ was synthesized from rhodamine 6 G, and its structure was characterized by Nuclear magnetic resonance spectroscopy, infrared spectroscopy, and mass spectrometry. The probe showed good selectivity for Al3+ and formed a fluorescent system with strong anti-interference ability. The fluorescence intensity of the probe solution was positively correlated with the concentration of Al3+, with an LOD of 1.08 x 10- 8 mol/L, with good accuracy and precision. The two are reversibly combined in a 1:1 way. The optimal time for the reaction was 5 min, and the optimal pH was 7. It speculated the possible detection mechanism. In addition, the NJQ probe was successfully applied to determine Al3+ in tap water, and cytotoxicity and fluorescence imaging tests were performed. The results showed that the probe has potential practical applications.
引用
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页数:6
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